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Which of the following is not organometa...

Which of the following is not organometallic complex?

A

Grignard reagent

B

Ferrocene

C

Trans-platin

D

Diethyl zinc

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AI Generated Solution

The correct Answer is:
To determine which of the following is not an organometallic complex, we need to understand what constitutes an organometallic compound. An organometallic compound is defined as a compound that contains a metal (M) bonded to a carbon atom (C) through a covalent bond. Let's analyze the given options step by step: 1. **Identify the Components**: - Organometallic compounds typically consist of a metal and a carbon-containing group (like alkyl or aryl groups). 2. **Evaluate Each Option**: - **Option 1: R-Mg-X (e.g., CH3-Mg-X)**: - Here, Mg is the metal and it is bonded to a carbon atom (CH3). This is a sigma bond, making it an organometallic compound. - **Option 2: Ferrocene**: - Ferrocene consists of an iron (Fe) atom sandwiched between two cyclopentadienyl anions (C5H5). The bonding involves pi donation from the ligands to the metal, classifying it as a pi organometallic compound. - **Option 3: Trans-platinum (trans-PtCl2(NH3)2)**: - In this complex, platinum (Pt) is bonded to chlorine (Cl) and ammonia (NH3) but there is no carbon present in this structure. Therefore, it does not qualify as an organometallic compound. - **Option 4: Diethyl zinc (C2H5)2Zn**: - This compound contains zinc (Zn) bonded to two ethyl groups (C2H5). The bond between Zn and carbon makes it an organometallic compound. 3. **Conclusion**: - After evaluating all the options, the only compound that does not contain a carbon atom bonded to the metal is **trans-platinum (trans-PtCl2(NH3)2)**. Therefore, this is the correct answer to the question. ### Final Answer: **Trans-platinum (trans-PtCl2(NH3)2) is not an organometallic complex.**
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AAKASH INSTITUTE- ALCOHOLS, PHENOLS AND ETHERS-Assignment Section -D (Assertion - reason type question)
  1. Which of the following is not organometallic complex?

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  2. A : p - nitrophenol has high pK(a) in comparison to o-nitrophenol ...

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  3. A : When C(2) H(5) - O- CH(3) is reacted with oen mole of Hl then C(2...

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  4. A : When 3,3-dimethyl butan - 2 - ol is heated in presence of concentr...

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  5. A : In esterification reaction , HCOOH is the most reactive acid among...

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  6. A : Ethers can't be distilled upto dryness due to fear of explosion . ...

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  7. A : Phenol does not react with NaHCO(3) . R : Phenol is less acid...

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  8. A : CH(3) - underset(O)underset(||)(C)-COOH gives haloform reaction ...

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  9. A : Diphenyl ether is prepared by Williamson synthesis . R : This...

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  10. A : Grignard's reagent is prepared in the presence of ether . R :...

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  11. A : CH(3) - underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-CH=...

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  12. A : Two moles of Grignard reagent is consumed in the formation of ter...

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  13. A : CH(3)-underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-O-CH...

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  14. A : Ortho - cresol is weaker acidic than meta-cresol . R : It is d...

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  15. A : Among all ortho halophenol , fluorophenol is least acidic . R ...

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  16. A : In esterification reaction alcohol act as nucleophile . R : ...

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  17. A : Phenol is manufactured by Dow 's pocess. R : It involves the ...

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  18. A : Primary alcohol is prepared by the reaction of primary amine with ...

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  19. A : Thte reactivity order of alcohols is 1^(@) gt 2^(@) gt 3^(@) for...

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  20. A : The dehydration of ethyl alcohol in presence of Al(2)O(2) at 633 ...

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