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. How many optical isomers are possible ...

. How many optical isomers are possible for [MABCD], where M is dsp2 hybridized?

A

1

B

2

C

3

D

Zero

Text Solution

AI Generated Solution

The correct Answer is:
To determine how many optical isomers are possible for the coordination compound [MABCD], where M is dsp² hybridized, we can follow these steps: ### Step 1: Identify the Hybridization and Geometry - The given metal M is dsp² hybridized. This hybridization indicates that the geometry of the complex is square planar. ### Step 2: Understand the Structure of the Complex - In a square planar complex, there are four coordination sites around the metal center. The ligands A, B, C, and D occupy these sites. ### Step 3: Analyze the Ligands - The ligands A, B, C, and D are all different. This is important because the uniqueness of the ligands can lead to potential optical isomers. ### Step 4: Determine the Plane of Symmetry - For a molecule to exhibit optical isomerism, it must lack a plane of symmetry. A plane of symmetry is an imaginary plane that divides the molecule into two mirror-image halves. - In the case of the square planar complex [MABCD], we can analyze the arrangement of the ligands: - If we try to draw a plane of symmetry, we can see that the arrangement of A, B, C, and D does not allow for a plane that divides the complex into two equal halves. For example, if we place A and B on one side and C and D on the other, they do not mirror each other. ### Step 5: Conclusion on Optical Isomers - Since the square planar complex [MABCD] has a plane of symmetry, it does not exhibit optical isomerism. - Therefore, the number of optical isomers for [MABCD] is **0**. ### Final Answer The number of optical isomers possible for [MABCD] is **0**. ---
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