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A: The degeneracy of d-orbitals is lost ...

A: The degeneracy of d-orbitals is lost under strong field ligand
R: The degeneracy of d-orbitals does not get lost under weak field ligand

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2).

C

) If Assertion is true statement but Reason is false, then mark (3).

D

If both Assertion and Reason are false statements, then mark (4)

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AI Generated Solution

The correct Answer is:
To analyze the given assertion and reason regarding the degeneracy of d-orbitals in the presence of strong and weak field ligands, we can break down the explanation into a step-by-step solution. ### Step-by-Step Solution: **Step 1: Understanding Degeneracy of d-Orbitals** - **Definition**: Degeneracy refers to the condition where multiple orbitals have the same energy level. In the case of d-orbitals, there are five orbitals (dxy, dyz, dxz, dx2-y2, dz2) that are degenerate when isolated, meaning they all have the same energy. **Step 2: Effect of Ligands on d-Orbitals** - **Ligand Interaction**: When ligands approach a metal ion, they interact with the d-orbitals. The nature of this interaction depends on whether the ligands are strong field or weak field ligands. - **Strong Field Ligands**: Strong field ligands cause a significant splitting of the d-orbitals due to stronger interactions, leading to a loss of degeneracy. This means that the energy levels of the d-orbitals become unequal. - **Weak Field Ligands**: Weak field ligands cause a smaller degree of splitting, but they also result in a loss of degeneracy, albeit to a lesser extent than strong field ligands. **Step 3: Conclusion on Assertion and Reason** - **Assertion (A)**: "The degeneracy of d-orbitals is lost under strong field ligand." - This statement is **True** because strong field ligands cause significant splitting of the d-orbitals. - **Reason (R)**: "The degeneracy of d-orbitals does not get lost under weak field ligand." - This statement is **False** because weak field ligands also cause a loss of degeneracy, just to a lesser extent than strong field ligands. **Final Conclusion**: The assertion is true, but the reason is false. Therefore, the correct answer is that the assertion is true, but the reason provided is not correct.
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AAKASH INSTITUTE- ALCOHOLS, PHENOLS AND ETHERS-Assignment Section -D (Assertion - reason type question)
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  3. A : When C(2) H(5) - O- CH(3) is reacted with oen mole of Hl then C(2...

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  4. A : When 3,3-dimethyl butan - 2 - ol is heated in presence of concentr...

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  5. A : In esterification reaction , HCOOH is the most reactive acid among...

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  6. A : Ethers can't be distilled upto dryness due to fear of explosion . ...

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  7. A : Phenol does not react with NaHCO(3) . R : Phenol is less acid...

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  8. A : CH(3) - underset(O)underset(||)(C)-COOH gives haloform reaction ...

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  9. A : Diphenyl ether is prepared by Williamson synthesis . R : This...

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  10. A : Grignard's reagent is prepared in the presence of ether . R :...

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  11. A : CH(3) - underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-CH=...

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  12. A : Two moles of Grignard reagent is consumed in the formation of ter...

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  13. A : CH(3)-underset(CH(3))underset(|)overset(CH(3))overset(|)(C)-O-CH...

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  14. A : Ortho - cresol is weaker acidic than meta-cresol . R : It is d...

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  15. A : Among all ortho halophenol , fluorophenol is least acidic . R ...

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  16. A : In esterification reaction alcohol act as nucleophile . R : ...

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  17. A : Phenol is manufactured by Dow 's pocess. R : It involves the ...

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  18. A : Primary alcohol is prepared by the reaction of primary amine with ...

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  19. A : Thte reactivity order of alcohols is 1^(@) gt 2^(@) gt 3^(@) for...

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  20. A : The dehydration of ethyl alcohol in presence of Al(2)O(2) at 633 ...

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