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A:CN^(-) is an acid ligand. R: CN^(-) ac...

A:`CN^(-)` is an acid ligand. R: `CN^(-)` accepts electron pair also.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1)

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2).

C

) If Assertion is true statement but Reason is false, then mark (3).

D

If both Assertion and Reason are false statements, then mark (4)

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given statements about the ligand CN^(-), we will break down the assertion and reason step by step. ### Step 1: Understand the Assertion The assertion states that CN^(-) is an acid ligand. - **Analysis**: - A ligand is a species that can donate a pair of electrons to a metal center in a coordination compound. - Acid ligands typically refer to species that can accept electron pairs, which is contrary to the behavior of CN^(-). ### Step 2: Evaluate the Assertion - Since CN^(-) is known to be a strong field ligand and acts as a Lewis base (donating electron pairs), it cannot be classified as an acid ligand. **Conclusion for Assertion**: The assertion is **false**. ### Step 3: Understand the Reason The reason states that CN^(-) accepts an electron pair. - **Analysis**: - Accepting an electron pair is characteristic of Lewis acids, while donating an electron pair is characteristic of Lewis bases. - CN^(-) is a Lewis base because it has a lone pair of electrons that it can donate. ### Step 4: Evaluate the Reason - Since CN^(-) does not accept electron pairs but rather donates them, the reason is also incorrect. **Conclusion for Reason**: The reason is **false**. ### Final Conclusion Both the assertion and the reason are false. Therefore, the correct answer is that both statements are incorrect.
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AAKASH INSTITUTE- ALCOHOLS, PHENOLS AND ETHERS-Assignment Section -D (Assertion - reason type question)
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  8. A : CH(3) - underset(O)underset(||)(C)-COOH gives haloform reaction ...

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  9. A : Diphenyl ether is prepared by Williamson synthesis . R : This...

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  10. A : Grignard's reagent is prepared in the presence of ether . R :...

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  15. A : Among all ortho halophenol , fluorophenol is least acidic . R ...

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  16. A : In esterification reaction alcohol act as nucleophile . R : ...

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  17. A : Phenol is manufactured by Dow 's pocess. R : It involves the ...

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  18. A : Primary alcohol is prepared by the reaction of primary amine with ...

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  19. A : Thte reactivity order of alcohols is 1^(@) gt 2^(@) gt 3^(@) for...

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