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The number of isomers possible for the m...

The number of isomers possible for the molecular formula `C_(2)` FCIBrl is

A

2

B

3

C

4

D

6

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AI Generated Solution

The correct Answer is:
To determine the number of isomers possible for the molecular formula C₂FClBrI, we will follow these steps: ### Step 1: Determine the Structure The molecular formula C₂FClBrI indicates that we have 2 carbon atoms and 4 halogen atoms (F, Cl, Br, I). ### Step 2: Calculate the Double Bond Equivalent (DBE) The formula for calculating the Double Bond Equivalent (DBE) is: \[ \text{DBE} = C + 1 - \frac{H + N + X}{2} \] Where: - \(C\) = number of carbon atoms - \(H\) = number of hydrogen atoms - \(N\) = number of nitrogen atoms - \(X\) = number of halogen atoms For C₂FClBrI: - \(C = 2\) - \(H = 0\) (since there are no hydrogen atoms in the formula) - \(N = 0\) (no nitrogen atoms) - \(X = 4\) (F, Cl, Br, I) Substituting the values: \[ \text{DBE} = 2 + 1 - \frac{0 + 0 + 4}{2} = 3 - 2 = 1 \] ### Step 3: Identify Possible Structures A DBE of 1 indicates that there is either a double bond or a ring. However, since we only have 2 carbon atoms, a ring structure is not feasible. Therefore, we will have a carbon-carbon double bond. ### Step 4: Draw Possible Isomers With the carbon-carbon double bond, we can arrange the halogens around the double bond. The possible arrangements can be: 1. **C=C with different halogens on each carbon**: - C1: F, C2: Cl - C1: F, C2: Br - C1: F, C2: I - C1: Cl, C2: Br - C1: Cl, C2: I - C1: Br, C2: I ### Step 5: Consider Geometric Isomers Since we have different halogens attached to the double bond, we can also have cis/trans isomers: - For example, if we take F and Cl on one carbon and Br and I on the other, we can have: - **Cis Isomer**: Both higher priority groups (based on atomic number) on the same side. - **Trans Isomer**: Higher priority groups on opposite sides. ### Step 6: Count the Isomers From the arrangements, we can derive the following isomers: 1. **Cis and Trans Isomers** for each arrangement of halogens. After analyzing all possible configurations, we find that there are a total of **6 unique isomers** (considering cis and trans). ### Final Answer The number of isomers possible for the molecular formula C₂FClBrI is **6**. ---
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AAKASH INSTITUTE-HALOALKANES AND HALOARENES -EXERCISE
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  11. Identity Z in the following sequence

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  12. Most reactive halide towards S(N^(1)) reactions is

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  13. Which of the following is most reactive toward nucleophilic substituti...

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