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Which of the following is an example of ...

Which of the following is an example of 1,2 -elimation ?

A

`CH_(3)-underset(Br)underset(|)(CH)-CH_(3) overset("Reagent")(rarr)CH_(4)-CH=CH_(2)`

B

C

`H_(2)underset(X)underset(|)(C)-CH_(2)-CH_(2)-underset(Y)underset(|)(CH_(2))overset("Reagent")(rarr)H_(3)C-CH=CH-CH_(3)`

D

All of these

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The correct Answer is:
To determine which of the given options is an example of 1,2-elimination, we need to analyze the reactions and the positions from which the groups are eliminated. ### Step-by-Step Solution: 1. **Understanding 1,2-Elimination**: - In a 1,2-elimination reaction, two groups (usually a leaving group and a hydrogen atom) are removed from adjacent carbon atoms (the first and second carbon). This results in the formation of a double bond between these two carbons. 2. **Identifying the Reaction**: - The question refers to a reaction where a hydroxide ion (OH⁻) abstracts a beta hydrogen from the beta position of a substrate in the presence of alcoholic KOH. - For example, if we have a compound where the leaving group (X) is on carbon 1 and a hydrogen on carbon 2, the elimination will yield an alkene. 3. **Analyzing the Options**: - **Option 1**: If the reaction involves the removal of a leaving group (X) from carbon 1 and a hydrogen from carbon 2, it is a 1,2-elimination. - **Option 2**: This is a Wurtz reaction, where two halides are removed from carbon 1 and carbon 3, resulting in a 1,3-elimination. - **Option 3**: If the elimination occurs from carbon 1 and carbon 4, it is a 1,4-elimination. 4. **Conclusion**: - The correct answer is the option where the elimination occurs from adjacent carbons (1 and 2). This is the only scenario that qualifies as a 1,2-elimination. ### Final Answer: The example of 1,2-elimination is the reaction where a leaving group is removed from carbon 1 and a hydrogen from carbon 2, leading to the formation of an alkene.
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AAKASH INSTITUTE-HALOALKANES AND HALOARENES -EXERCISE
  1. 2-Chloro-2-methylpropane on reaction with aqueous KOH gives X as the m...

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  2. Which of the following does not form Grignard reagent on reaction with...

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  3. 1-phenyl-2-chloropropane on treating with alc. KOH gives mainly

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  4. An alkyl halide on reaction with sodium in the presence of ether gives...

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  5. Ethyl bromide reacts with lead sodium alloy to form:

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  6. Allybromide on dehydrobromination gives

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  7. Identify the major product

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  8. Identify the most suitable reagent for the following conversion ? C...

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  9. Which of the following is an example of 1,2 -elimation ?

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  10. The carbocation is the intermediate in

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  11. IUPAC name of Gammexene is

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  12. Pyrene is trade name of when used as fire extinguisher

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  13. Which of the following with aqueous KOH will give acetaldehyde ?

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  14. Carbylamine test is performed in alcoholic KOH by heating a mixture of...

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  15. What happens when C Cl(4) is treated with AgNO(3) solution ?

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  16. DDT is formed from

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  17. Iodoform in medicines is used as

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  18. If chloroform is left open in the air in the presence of sunlight

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  19. Non - sticking frying pans are coated with teflon which is polymer of

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  20. Which of the following are arranged in the decreasing order of dipole ...

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