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C(6) H(5)N2^+Cl^-overset(Cu(2)Cl(2)//HCl...

`C_(6) H_(5)N2^+Cl^-overset(Cu_(2)Cl_(2)//HCl)(rarr)` , this reaction is named as

A

Sandmeyer

B

Swarts

C

Wurtz-fitting

D

Finkelstein

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of the diazonium salt \( C_6H_5N_2^+Cl^- \) with \( Cu_2Cl_2 \) in the presence of \( HCl \), we need to identify the product formed and the name of the reaction. ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactant is a diazonium salt, specifically \( C_6H_5N_2^+Cl^- \), which is a benzene ring with a diazonium group (N2^+) and a chloride ion. 2. **Understand the Reaction Conditions**: The reaction takes place in the presence of \( Cu_2Cl_2 \) and \( HCl \). The copper(I) chloride (\( CuCl \)) acts as a reagent that facilitates the substitution reaction. 3. **Recognize the Type of Reaction**: In this reaction, the diazonium group (N2^+) is a good leaving group. When it leaves, it is replaced by a chlorine atom from \( Cu_2Cl_2 \). 4. **Determine the Product**: The product formed from this reaction is chlorobenzene (\( C_6H_5Cl \)). The diazonium group is replaced by a chlorine atom. 5. **Name the Reaction**: This type of reaction is known as the **Sandmeyer Reaction**. It is a well-known reaction in organic chemistry used to synthesize aryl halides from aryl diazonium salts. ### Final Answer: The reaction \( C_6H_5N_2^+Cl^- \overset{Cu_2Cl_2/HCl}{\rightarrow} C_6H_5Cl \) is called the **Sandmeyer Reaction**. ---
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