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CH=CHoverset(HgSO(4))underset(H(2)SO(4))...

`CH=CHoverset(HgSO_(4))underset(H_(2)SO_(4))toXoverset(LiAlH_(4))toY`.
In the above reaction, X and Y are

A

Ethanal, Ethanol

B

Ethanol, Ethanal

C

Ethanal, Ethanoic acid

D

Ethanoic acid, Acetone

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we will analyze the reactions step by step. ### Step 1: Identify the starting compound The starting compound is an alkyne represented as CH=CH. This is ethyne (acetylene). ### Step 2: Reaction with HgSO4 and H2SO4 When ethyne (CH≡CH) reacts with mercuric sulfate (HgSO4) in the presence of sulfuric acid (H2SO4), it undergoes hydration to form an enol, which can tautomerize to a ketone. 1. The reaction proceeds through the formation of a non-classical carbocation. 2. Water (H2O) acts as a nucleophile and attacks the carbocation, leading to the formation of an enol. 3. The enol then undergoes keto-enol tautomerism to form a ketone. The product after this reaction (X) is **ethanol (CH3CHO)**. ### Step 3: Reaction with LiAlH4 Next, the product X (ethanol) is treated with lithium aluminum hydride (LiAlH4), which is a strong reducing agent. 1. LiAlH4 reduces aldehydes to primary alcohols. 2. Therefore, the aldehyde (ethanol) will be reduced to its corresponding alcohol. The product after this reaction (Y) is **ethanol (CH3CH2OH)**. ### Final Products - **X**: Ethanal (CH3CHO) - **Y**: Ethanol (CH3CH2OH) ### Summary of the Reaction - The reaction starts with ethyne (CH≡CH), which converts to ethanal (X) upon reaction with HgSO4 and H2SO4. - The ethanal (X) is then reduced to ethanol (Y) by LiAlH4. ### Final Answer - X = Ethanal (CH3CHO) - Y = Ethanol (CH3CH2OH)
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