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Reduction of cyclohex-2-enone with alumi...

Reduction of cyclohex-2-enone with aluminium isopropoxide in excess of isopropyl alcohol with produce

A

Cyclohexanol

B

Cyclohex-2-enol

C

Cyclohexanone

D

Benzene

Text Solution

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The correct Answer is:
To solve the question regarding the reduction of cyclohex-2-enone with aluminium isopropoxide in excess isopropyl alcohol, we will follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The starting compound is cyclohex-2-enone, which has a structure of a cyclohexane ring with a ketone (C=O) group at the second position and a double bond (C=C) between the first and second carbon atoms. 2. **Understand the Reaction Conditions**: - The reaction involves aluminium isopropoxide (Al(OPr)₃) as a reducing agent and isopropyl alcohol (IPA) in excess. This combination is known for reducing ketones and aldehydes to their corresponding alcohols. 3. **Recognize the Type of Reaction**: - This reaction is classified as an MPV (Meerwein-Ponndorf-Verley) reduction. In this reaction, the ketone functional group will be reduced to an alcohol while the double bond in the cyclohexene remains intact. 4. **Perform the Reduction**: - During the reduction, the carbonyl group (C=O) of cyclohex-2-enone will be converted to a hydroxyl group (C-OH), resulting in the formation of cyclohex-2-en-1-ol. The double bond in the cyclohexene will not be affected. 5. **Write the Final Product**: - The final product after the reduction is cyclohex-2-en-1-ol. This compound retains the double bond from the original cyclohex-2-enone but now has an alcohol functional group. ### Final Answer: The reduction of cyclohex-2-enone with aluminium isopropoxide in excess isopropyl alcohol produces cyclohex-2-en-1-ol. ---
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