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Which of the following species will give...

Which of the following species will give aldol condensation?

A

HCHO

B

Salicyldehyde

C

`(CH_(3))_(3)C CHO`

D

`PhCH_(2)CHO`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which species will undergo aldol condensation, we need to follow these steps: ### Step 1: Understand the Requirements for Aldol Condensation Aldol condensation requires: - The presence of at least one aldehyde or ketone. - The presence of at least one alpha hydrogen (hydrogens attached to the carbon adjacent to the carbonyl group). ### Step 2: Analyze Each Given Option We will evaluate each option to see if it meets the criteria for aldol condensation. #### Option A: HCHO (Formaldehyde) - **Type**: Aldehyde - **Alpha Hydrogen**: No alpha hydrogen is present because there is no alpha carbon (the carbon attached to the carbonyl carbon). - **Conclusion**: Does not undergo aldol condensation. #### Option B: Salicylic Aldehyde - **Structure**: Contains a benzene ring with an -OH group and an -CHO group. - **Alpha Hydrogen**: There are no alpha hydrogens because the carbon adjacent to the carbonyl is fully bonded (no hydrogens available). - **Conclusion**: Does not undergo aldol condensation. #### Option C: CH3CHO (Acetaldehyde) - **Type**: Aldehyde - **Alpha Hydrogen**: There is one alpha hydrogen present (the methyl group has three hydrogens). - **Conclusion**: Undergoes aldol condensation. #### Option D: pH-CH2-CHO - **Structure**: Contains a phenyl group (pH) and an aldehyde group (CHO). - **Alpha Hydrogen**: The CH2 group has two alpha hydrogens. - **Conclusion**: Undergoes aldol condensation. ### Final Conclusion Among the given options: - **Option C (CH3CHO)** and **Option D (pH-CH2-CHO)** will undergo aldol condensation. - **Options A (HCHO)** and **B (Salicylic Aldehyde)** will not. ### Summary of Results - **Aldol Condensation Possible**: CH3CHO, pH-CH2-CHO - **Aldol Condensation Not Possible**: HCHO, Salicylic Aldehyde ---
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