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"Acetaldehyde"overset(HCN)toXoverset(H(2...

`"Acetaldehyde"overset(HCN)toXoverset(H_(2)O //H^(+))toYoverset("Heat")toZ`
In the above sequence, the end product Z is

A

Prop-2-enoic acid

B

But-2-enoic acid

C

Lactic acid

D

Tartaric acid

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will go through the reactions step by step: ### Step 1: Reaction of Acetaldehyde with HCN - **Starting Compound:** Acetaldehyde (CH₃CHO) - **Reagent:** HCN (Hydrogen cyanide) In this step, the cyanide ion (CN⁻) acts as a nucleophile and attacks the electrophilic carbon of the carbonyl group in acetaldehyde. This results in the formation of a cyanohydrin. **Reaction:** \[ \text{CH}_3\text{CHO} + \text{HCN} \rightarrow \text{CH}_3\text{C(OH)(CN)} \] - **Product X:** CH₃C(OH)(CN) ### Step 2: Hydrolysis of the Cyanohydrin (X) - **Starting Compound:** Cyanohydrin (CH₃C(OH)(CN)) - **Reagent:** Water (H₂O) in the presence of an acid (H⁺) During hydrolysis, the cyanide group (CN) is converted into a carboxylic acid (COOH), while the hydroxyl group remains. Ammonia (NH₃) is released as a byproduct. **Reaction:** \[ \text{CH}_3\text{C(OH)(CN)} + \text{H}_2\text{O} \rightarrow \text{CH}_3\text{C(OH)(COOH)} + \text{NH}_3 \] - **Product Y:** CH₃C(OH)(COOH) ### Step 3: Heating the Product (Y) - **Starting Compound:** Hydroxy acid (CH₃C(OH)(COOH)) When heated, the hydroxy group (OH) and a hydrogen atom (H) from the carboxylic acid group (COOH) are eliminated as water (H₂O), leading to the formation of an α,β-unsaturated carboxylic acid. **Reaction:** \[ \text{CH}_3\text{C(OH)(COOH)} \xrightarrow{\text{Heat}} \text{CH}_2=CH\text{COOH} + \text{H}_2\text{O} \] - **Product Z:** CH₂=CHCOOH ### Final Product The final product Z is **CH₂=CHCOOH**, which is known as **acrylic acid** or **prop-2-enoic acid**. ### Summary of Products - **X:** CH₃C(OH)(CN) (Cyanohydrin) - **Y:** CH₃C(OH)(COOH) (Hydroxy acid) - **Z:** CH₂=CHCOOH (Acrylic acid) ### Answer The end product Z is **acrylic acid (CH₂=CHCOOH)**. ---
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