Home
Class 12
CHEMISTRY
"Propionic acid"overset(PCl(5))toXoverse...

`"Propionic acid"overset(PCl_(5))toXoverset(C_(6)H_(6))underset(AlCl_(3))toY`.
In the above sequence Y is

A

Phenylethylketone

B

Phenylacetate

C

Ethyl benzene

D

Ethyl benzoate

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will follow the steps of the reaction sequence given in the question. ### Step 1: Identify the structure of Propionic Acid Propionic acid has the molecular formula C3H6O2. Its structure can be represented as: \[ \text{CH}_3\text{CH}_2\text{COOH} \] This is a carboxylic acid with three carbon atoms. ### Step 2: Reaction of Propionic Acid with PCl5 When propionic acid reacts with phosphorus pentachloride (PCl5), it undergoes a substitution reaction where the hydroxyl (-OH) group of the carboxylic acid is replaced by a chlorine atom, forming an acyl chloride. The reaction can be represented as: \[ \text{CH}_3\text{CH}_2\text{COOH} + \text{PCl}_5 \rightarrow \text{CH}_3\text{CH}_2\text{COCl} + \text{POCl}_3 + \text{HCl} \] The product of this reaction, which we will denote as X, is propionyl chloride: \[ X = \text{CH}_3\text{CH}_2\text{COCl} \] ### Step 3: Reaction of X (Propionyl Chloride) with Benzene in the presence of AlCl3 Next, we react the acyl chloride (X) with benzene (C6H6) in the presence of aluminum chloride (AlCl3), which acts as a Lewis acid. This reaction is an electrophilic aromatic substitution. The acyl chloride generates an acylium ion (carbocation) which can be represented as: \[ \text{CH}_3\text{CH}_2\text{CO}^+ \] The benzene ring, being electron-rich, attacks this electrophile, leading to the formation of a ketone. The reaction can be represented as: \[ \text{C}_6\text{H}_6 + \text{CH}_3\text{CH}_2\text{CO}^+ \rightarrow \text{C}_6\text{H}_5\text{COCH}_2\text{CH}_3 \] The product Y formed from this reaction is phenyl ethyl ketone, which can also be written as: \[ Y = \text{C}_6\text{H}_5\text{COCH}_2\text{CH}_3 \] ### Conclusion Thus, the final product Y is phenyl ethyl ketone. ### Final Answer Y is phenyl ethyl ketone. ---
Promotional Banner

Similar Questions

Explore conceptually related problems

C_(6)H_(6)overset(HNO_(3))underset(H_(2)SO_(4))rarr X overset(Cl_(2))underset(FeCl_(3))rarr Y In the above sequence Y can be

C_(2)H_(6)overset((CH_(3)COO)_(2)Mn)rarr X overset(PCl_(5))rarr Y overset(C_(6)H_(6))underset("Anhy." AlCl_(3))rarr Z . Identify X, Y and Z :

CH=CHoverset(HgSO_(4))underset(H_(2)SO_(4))toXoverset(LiAlH_(4))toY . In the above reaction, X and Y are

Perdict the product (C) of the following sequence of reactions : CH_(3)COOHoverset(PCl_(5))rarr[A]overset(C_(6)H_(6))underset("Anhyd."AlCl_(3))rarr[B]overset(CH_(3)MgBr)underset(H_(2)O^(+))rarr[C]