Home
Class 12
CHEMISTRY
The product C of the reaction CH(3)Clo...

The product C of the reaction
`CH_(3)Cloverset(KCN)toAoverset(H_(2)O //H^(+))toBoverset(NH_(3))to`C is

A

`HCONH_(2)`

B

`CH_(3)CN`

C

`CH_(3)CH_(2)NH_(2)`

D

`CH_(3)CONH_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the reactions involved in the transformation from compound A to compound C. ### Step 1: Reaction of CH₃Cl with KCN - **Reactants**: CH₃Cl (methyl chloride) and KCN (potassium cyanide). - **Mechanism**: The cyanide ion (CN⁻) acts as a nucleophile and attacks the carbon atom in CH₃Cl, which is partially positive due to the electronegativity of chlorine. Chlorine, being a good leaving group, departs as Cl⁻. - **Product**: The product formed is CH₃CN (methyl cyanide or acetonitrile). ### Step 2: Hydrolysis of CH₃CN - **Reactant**: CH₃CN (methyl cyanide). - **Conditions**: The reaction is carried out in the presence of water (H₂O) and an acid (H⁺). - **Mechanism**: The triple bond in CH₃CN is hydrolyzed. The water molecule acts as a nucleophile, attacking the carbon atom of the nitrile group (C≡N). The reaction proceeds through the formation of an intermediate, leading to the formation of CH₃COOH (acetic acid) and NH₄⁺ (ammonium ion). - **Product**: The product formed is CH₃COOH (acetic acid). ### Step 3: Reaction of CH₃COOH with NH₃ - **Reactants**: CH₃COOH (acetic acid) and NH₃ (ammonia). - **Mechanism**: Ammonia reacts with acetic acid to form an amide. The reaction involves the nucleophilic attack of NH₃ on the carbonyl carbon of acetic acid, leading to the formation of CH₃CONH₂ (acetamide) and the release of a water molecule. - **Product**: The final product formed is CH₃CONH₂ (acetamide). ### Final Product The final product C of the reaction sequence is **CH₃CONH₂ (acetamide)**. ---
Promotional Banner

Similar Questions

Explore conceptually related problems

The product D of the reaction CH_(3)Cl overset( KCN) ( rarr) ( A) overset( H_(2) O) ( rarr) (B) overset( NH_(3))(rarr) ( C ) overset( Delta)( rarr) ( D ) is

The product D in the following reaction is ___________. CH_(3)Cloverset(KCN)to(A)overset(H_(2)O)to(B)overset(NH_(3))to(C)overset(Delta)to(D)

Identify A, B and C in the following reactions : (i) CH_(3)CH_(2)Cloverset(KCN)toA overset(H_(2)//Ni)toBoverset(CH_(3)COCl//Base)toC (ii) C_(6)H_(5)N_(2)^(+)Cl^(-)overset(HBF_(4))toAunderset(Delta)overset(NaNO_(2)//Cu)toBoverset(Sn//HCl)toC