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A : In crossed Cannizzaro's reaction in ...

A : In crossed Cannizzaro's reaction in between HCHO and `C_(6)H_(5)CHO`, HCHO is oxidised.
R : `OH^(-)` firstly attacks on HCHO. So, HCHO is oxidised.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1).

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2).

C

If Assertion is true statement but Reason is false, then mark (3).

D

If both Assertion and Reason are false statements, then mark (4).

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the crossed Cannizzaro reaction between formaldehyde (HCHO) and benzaldehyde (C₆H₅CHO), we will analyze the statements provided: **Statement A:** In the crossed Cannizzaro reaction between HCHO and C₆H₅CHO, HCHO is oxidized. **Statement R:** OH⁻ firstly attacks HCHO. So, HCHO is oxidized. ### Step-by-Step Solution: 1. **Understanding Cannizzaro Reaction:** - The Cannizzaro reaction occurs when aldehydes that do not have alpha-hydrogens undergo disproportionation in the presence of a strong base (like NaOH or KOH). - In this reaction, one molecule of the aldehyde is oxidized to a carboxylic acid, while another molecule is reduced to an alcohol. 2. **Identifying the Reactants:** - The two aldehydes involved in the reaction are formaldehyde (HCHO) and benzaldehyde (C₆H₅CHO). - HCHO has no alpha-hydrogens, making it suitable for the Cannizzaro reaction. Benzaldehyde also lacks alpha-hydrogens. 3. **Mechanism of the Reaction:** - In the presence of OH⁻ (hydroxide ion), it acts as a nucleophile and attacks the carbonyl carbon of HCHO. - The attack results in the formation of a tetrahedral intermediate, which then leads to the formation of a carboxylate ion (HCOO⁻) and a hydride ion (H⁻). 4. **Hydride Transfer:** - The hydride ion (H⁻) generated from the oxidation of HCHO can then be transferred to the electrophilic carbon of benzaldehyde (C₆H₅CHO). - This transfer results in the reduction of benzaldehyde to benzyl alcohol (C₆H₅CH₂OH). 5. **Final Products:** - The final products of the reaction are formic acid (HCOOH) from the oxidation of HCHO and benzyl alcohol (C₆H₅CH₂OH) from the reduction of benzaldehyde. 6. **Conclusion:** - Since HCHO is indeed oxidized to formic acid, Statement A is correct. - The reason provided (Statement R) is also correct, as OH⁻ does attack HCHO first, leading to its oxidation. - Therefore, both statements A and R are true, and R is the correct explanation for A. ### Final Answer: Both Statement A and Statement R are correct, and R is the correct explanation for A. ---
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