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A : H(2)N-overset(O)overset(||)(C)-CH(3)...

A : `H_(2)N-overset(O)overset(||)(C)-CH_(3)` can give iodoform reaction.
R : `Cl-overset(O)overset(||)(C)-CH_(3)` can also give iodoform reaction due to presence of `-COCH_(3)` group.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1).

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2).

C

If Assertion is true statement but Reason is false, then mark (3).

D

If both Assertion and Reason are false statements, then mark (4).

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given statements about the iodoform reaction, we will break down the assertion and reason step by step. ### Step-by-Step Solution: 1. **Understanding the Assertion:** - The assertion states that `H2N-CO-CH3` (Acetamide) can give an iodoform reaction. - The iodoform reaction typically requires a methyl ketone (R-CO-CH3) or a compound that can be oxidized to form a methyl ketone. 2. **Analyzing the Structure of Acetamide:** - Acetamide has the structure `H2N-CO-CH3`. - It contains a carbonyl group (C=O) and a methyl group (CH3) attached to the carbonyl carbon. - However, acetamide itself does not have a methyl ketone structure directly; it is an amide. 3. **Conclusion on Assertion:** - Since acetamide does not directly fit the criteria for the iodoform reaction (which requires a methyl ketone), the assertion is **false**. 4. **Understanding the Reason:** - The reason states that `Cl-CO-CH3` (Chloroacetone) can also give an iodoform reaction due to the presence of the `-CO-CH3` group. - Chloroacetone has the structure `Cl-CO-CH3`, which indeed contains a methyl ketone structure. 5. **Analyzing the Structure of Chloroacetone:** - Chloroacetone has a carbonyl group (C=O) and a methyl group (CH3) attached to the carbonyl carbon. - This structure fits the criteria for the iodoform reaction, as it can be oxidized to form a methyl ketone. 6. **Conclusion on Reason:** - Since chloroacetone does fit the criteria for the iodoform reaction, the reason is **true**. 7. **Final Conclusion:** - The assertion is false, and the reason is true. Therefore, the statement that the reason correctly explains the assertion is incorrect. ### Final Answer: - Assertion: False - Reason: True - The reason does not correctly explain the assertion.
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