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A : Formaldehyde undergoes Cannizzaro re...

A : Formaldehyde undergoes Cannizzaro reaction in the presence of `H^(+)`.
R : Formaldehyde has two `alpha`-Hydrogen atoms.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1).

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2).

C

If Assertion is true statement but Reason is false, then mark (3).

D

If both Assertion and Reason are false statements, then mark (4).

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the statements given: **Statement A:** Formaldehyde undergoes Cannizzaro reaction in the presence of `H^(+)`. **Statement R:** Formaldehyde has two `alpha`-Hydrogen atoms. ### Step 1: Understanding the Cannizzaro Reaction The Cannizzaro reaction is a redox reaction that occurs with aldehydes lacking alpha-hydrogens when treated with a strong base (like NaOH) or sometimes in acidic conditions. In this reaction, one molecule of aldehyde is oxidized to a carboxylic acid, while another molecule is reduced to an alcohol. ### Step 2: Analyzing Formaldehyde Formaldehyde (HCHO) is the simplest aldehyde. Its structure can be represented as: ``` H | C = O | H ``` In this structure, we can see that formaldehyde has no alpha-hydrogens because it has only one carbon atom and thus no adjacent carbon atoms that could provide alpha-hydrogens. ### Step 3: Evaluating Statement A Since formaldehyde does not have any alpha-hydrogens, it can indeed undergo the Cannizzaro reaction, but it typically requires a basic medium (not acidic). Therefore, the statement that formaldehyde undergoes the Cannizzaro reaction in the presence of `H^(+)` is incorrect. ### Step 4: Evaluating Statement R Statement R claims that formaldehyde has two alpha-hydrogens. As we established earlier, formaldehyde does not have any alpha-hydrogens. Therefore, this statement is also incorrect. ### Conclusion Both statements A and R are false. Therefore, the correct conclusion is that both statements are incorrect. ### Final Answer Both statements A and R are false. ---
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Benzaldehyde cannot undergo Cannizzaro reaction.

(A) undergoes Cannizzaro reaction. The products are:

(A) Aromatic aldehydes as well as formaldehyde undergo Cannizzaro's reaction with strong alkali. (R) Aldehydes which have alpha -hydrogen atoms undergo Cannizzaro's reaction.

Formaldehyde gives Cannizzaro's reaction while acetaldehyde does not. Why ?

In Cannizzaro's reaction an aldehyde undergoes