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A : Ethanol undergoes haloform reaction....

A : Ethanol undergoes haloform reaction.
R : Ethanol can be oxidised into ethanal.

A

If both Assertion & Reason are true and the reason is the correct explanation of the assertion, then mark (1).

B

If both Assertion & Reason are true but the reason is not the correct explanation of the assertion, then mark (2).

C

If Assertion is true statement but Reason is false, then mark (3).

D

If both Assertion and Reason are false statements, then mark (4).

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correctness of the statements A and R, we will analyze each statement step by step. ### Step 1: Analyzing Statement A **Statement A:** Ethanol undergoes haloform reaction. - The haloform reaction typically occurs with methyl ketones or compounds that can be oxidized to methyl ketones. Ethanol (C2H5OH) can be oxidized to ethanal (acetaldehyde, CH3CHO), which is a necessary precursor for the haloform reaction. - In the presence of halogens (like iodine, I2) and a base (like sodium hydroxide, NaOH), ethanol can be converted to the corresponding haloform (in this case, iodoform, CHI3) through a series of reactions. ### Step 2: Analyzing Statement R **Statement R:** Ethanol can be oxidized into ethanal. - Ethanol can indeed be oxidized to ethanal. This can be done using mild oxidizing agents such as PCC (Pyridinium chlorochromate) or even with stronger oxidizing agents under controlled conditions. - The oxidation process involves the conversion of the hydroxyl group (-OH) in ethanol to a carbonyl group (C=O) in ethanal. ### Conclusion Both statements A and R are correct: - Ethanol undergoes the haloform reaction after being oxidized to ethanal. - Ethanol can be oxidized to ethanal. ### Final Answer Both A and R are true. ---
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