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Which of the following disaccharide in a...

Which of the following disaccharide in acidic medium is called invert sugar?

A

Lactose

B

Maltose.

C

Sucrose

D

All of these

Text Solution

AI Generated Solution

The correct Answer is:
To answer the question "Which of the following disaccharides in acidic medium is called invert sugar?", we can follow these steps: ### Step-by-Step Solution: 1. **Understanding Invert Sugar**: - Invert sugar is a mixture of glucose and fructose that is formed when sucrose (table sugar) is hydrolyzed in an acidic medium. The hydrolysis process breaks down sucrose into its constituent monosaccharides. 2. **Identifying the Disaccharide**: - The disaccharide in question is sucrose (C12H22O11). It is composed of one glucose molecule and one fructose molecule. 3. **Hydrolysis of Sucrose**: - When sucrose is treated with an acid (like hydrochloric acid) and water, it undergoes hydrolysis: \[ \text{Sucrose} \xrightarrow{\text{H}^+} \text{Glucose} + \text{Fructose} \] - This reaction leads to the formation of glucose (C6H12O6) and fructose (C6H12O6). 4. **Optical Activity**: - Sucrose is dextrorotatory, meaning it rotates plane-polarized light in a clockwise direction. The specific rotation of sucrose is +66.5 degrees. - Glucose is also dextrorotatory (+52.5 degrees), while fructose is levorotatory, rotating light in the opposite direction (-92 degrees). 5. **Calculating the Resulting Optical Rotation**: - After hydrolysis, the overall optical rotation can be calculated: \[ \text{Rotation from Glucose} (+52.5) + \text{Rotation from Fructose} (-92) = -39.5 \text{ degrees} \] - This means the resultant solution after hydrolysis rotates light in the counterclockwise direction, indicating that it has become levorotatory. 6. **Conclusion**: - Since the hydrolysis of sucrose in acidic medium results in a solution that rotates plane-polarized light in the opposite direction, it is termed "invert sugar". Therefore, the answer to the question is **sucrose**. ### Final Answer: The disaccharide in acidic medium that is called invert sugar is **sucrose**.
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