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A : Specific rotation of freshly prepare...

A : Specific rotation of freshly prepared aqueous solution of `alpha`- D (+) glucose and `beta` - D (+) glucose are same.
R : `alpha` - D (+) glucose and `beta` - D (+) glucose are epimers.

A

If both Assertion and Reason are true and the reason is the correct explanation of the assertion, then mark (1).

B

If both Assertion and Reason are true but the reason is not the correct explanation of the assertion, then mark (2).

C

If Assertion is true statement but Reason is false, then mark (3).

D

If both Assertion and Reason are false statements, then mark (4).

Text Solution

AI Generated Solution

The correct Answer is:
To solve the assertion-reason question, we need to analyze both the assertion (A) and the reason (R) provided. ### Step-by-Step Solution: 1. **Understanding the Assertion (A)**: - The assertion states that the specific rotation of freshly prepared aqueous solutions of α-D-glucose and β-D-glucose are the same. - Specific rotation refers to the degree to which a compound can rotate plane-polarized light, which can vary based on the molecular structure and concentration of the solution. - In the case of α-D-glucose and β-D-glucose, although they have different specific rotations in their crystalline forms (α-D-glucose has a specific rotation of +112° and β-D-glucose has +19°), when they are in a freshly prepared aqueous solution, they can exist in equilibrium, leading to an average specific rotation. 2. **Understanding the Reason (R)**: - The reason states that α-D-glucose and β-D-glucose are epimers. - Epimers are a type of diastereomer that differ in configuration at only one specific carbon atom. In the case of glucose, α-D-glucose and β-D-glucose differ in the configuration at the anomeric carbon (C1). - However, α-D-glucose and β-D-glucose are not epimers; they are classified as anomers because they differ in configuration at the anomeric carbon (C1) specifically. 3. **Evaluating the Truth of A and R**: - The assertion (A) is **true** because the specific rotation of the two forms can be the same when in aqueous solution due to their equilibrium. - The reason (R) is **false** because α-D-glucose and β-D-glucose are not epimers; they are anomers. 4. **Conclusion**: - Since the assertion is true and the reason is false, we conclude that the correct answer is that A is true and R is false. ### Final Answer: - Assertion (A) is true. - Reason (R) is false. - Therefore, the correct conclusion is that the assertion is true, but the reason is not a correct explanation for the assertion.
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