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Which one of the following reactions doe...

Which one of the following reactions does not occur?

A

`Cl_(2) + 2Br^(-) rarr Br_(2) + 2Cl^(-)`

B

`CIF_(3) + H_(2)O rarr HCl + HOF + F_(2)`

C

`2NaOH + Cl_(2) rarr `NaCl + NaOCl + `H_(2)`O Cold and Dil.

D

`Na_(2) SO_(3) + 2HCl rarr` 2NaCl + `SO_(2) + H_(2)`O

Text Solution

Verified by Experts

The correct Answer is:
B

`3 ClF_(3) + 6H_(2)O hArr 9 HF + HCl + 2HClO_(3)`
thus, reaction (b) do not occur.
The other reactions occurs as shown below.
(a) `Cl_(2) + 2Br^(-) rarr Br_(2) + 2Cl^(-)`
(c ) 2NaOH + `Cl_(2) rarr` NaCl + NaOCl + `H_(2)O` cold and dil.
(d) `Na_(2)SO_(3) + 2HCl rarr `2NaCl + `SO_(2) + H_(2)O`
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