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Questions based on methods of preparatio...

Questions based on methods of preparation of carboxylic acids

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Which of the following methods are used for the conversion of carboxylic acids into acid chlorides (RCOOHrarrRCOCl) ?

There are two step-up methods : (i) Grignard reagent and (ii) nitrile method, for the preparation of carboxylic acids from RX , Which method is suitable for the preparation of step-up carboxylic acid from the following RX ? Why ? Give the name of the acid also. (I) (II) (III) (IV) PhCI (V) (VI) (VII) (VIII) (IX) .