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In [Fe(CN)5(NO)]^(2-), Fe has +2 state. ...

In `[Fe(CN)_5(NO)]^(2-)`, Fe has `+2` state. It cannot be dicided by

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Assertion : The blue precipitate formed by the action of K_(4)[Fe(CN)_(6)] on Fe^(3+) and by that of K_(2)[Fe(CN)_(6)] on Fe^(2+) have the same composition Reasion : [Fe(CN)_(6)]^(3-) oxides Fe^(2+) to Fe^(3-) and itself gets reduced to [Fe(CN)_(6)]^(4-) .

Assertion : [Fe(CN)_6]^(3-) is weakly paramagnetic while [Fe(CN)_6]^(4-) is diamagnetic. Reason : [Fe(CN)_6]^(3-) has +3 oxidation state while [Fe(CN)_6]^(4-) has +2 oxidation state.

For the reaction, 3Zn^(2+)+2K_(4)[Fe(CN)_(6)]rarr K_(2)Zn_(3)[Fe(CN)_(6)]_(2)+6K^(+) , what will be the equivalent weight of K_(4)[Fe(CN)_(6)] , if the molecular weight of K_(4)[Fe(CN)_(6)] is M ?