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Exaplain Cannozzaro reaction with an exa...

Exaplain Cannozzaro reaction with an example.

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Aldehydes which do not have an `alpha` hydrogen atom, undergo self-oxidation and reduetion reaction on heating with conc alkali.
In this reaction one molecules of the aldehyde is reduced to alcohol while another is oxidised to carboxylic acid salt.
Example-1 `underset("Formaldehyde")(HCHO+HCHO)+KOH overset(Delta)to underset("Methyl alcohol")(CH_(3)OH) + underset("Potassium formate")(HCOOK)`
Example-2
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SUBHASH PUBLICATION-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-QUESTIONS
  1. How does benzaldehyde reacts with acetophenone in presence of dilute a...

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  2. Ethanal(CH3CHO) undergoes aldol condensation reaction.Give reason.

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  3. Exaplain Cannozzaro reaction with an example.

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  4. Identify A and B in the following reaction.

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  5. Acetaldehyde does not undergo Cannizzaro reaction. Why ?

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  6. Formaldehyde undergoes Cannizzaro's reaction. Give reason.

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  7. Given two uses of formaldehyde.

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  8. How are carboxylic acids prepared form Grignard regents ?

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  9. What are Y and Z in the following reactions ?

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  10. Complete the following reaction.

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  11. Complete the following reaction.

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  12. How are carboxylic acids prepared from nitriles ?

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  13. Carboxylic acids are more acidic than phenols. Give reason.

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  14. Explain the effect of electron withdrawing groups. [EWG] on the acidi...

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  15. What is the effect of electron withdrawing group on the acidity of car...

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  16. Explain the effect of electron donating group (EDG) on the acidity of ...

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  17. Among formic acid and acetic acid, which is more acidic ? Give reason...

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  18. How PCl(3), PCl(5) and SOCl(2) reacts with carboxylic acids ?

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  19. Write the chemical equation to convert ethanoic acid to ethanoic anhyd...

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  20. The equation for The reaction between carboxylic acdis and PCl(5)

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