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(a) Write the IUPAC name of [Co(NH3)4(H2...

(a) Write the IUPAC name of `[Co(NH_3)4(H_2O)Cl]Cl_2`
(b) Explain linkage isometrism with example.

Text Solution

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Tetraammineaquachloridocobalt (III) chloride.
(b) Two or more compounds having the same molecular formula but differing in the mode of attachment of ligands to the central metal ion are called linkage isomers. The phenomenon is called linkage isomerism
`[Co(NH_3)_5NO_2]Cl_2 and [Co(NH_3)_5ONO]Cl_2` yellowish brown red.
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