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Organic compounds A, B and C are aliphat...

Organic compounds A, B and C are aliphatic saturated hydroxyl compounds when they react with Lucas reagent (anhyd.`ZnCl_(2)`+ conc.HCl ), the following observations are made
(i) Compound A gave turbidity immediately.
(ii) Compound B gave turbidity after five minutes
(iii) Compound C gave turbidity only on heating. Identify the type of compound A, B and C.
(b) Complete the equation:
`C_(6)H_(5)COOH + HOC_(6)H_(5) overset(H+)(to)`
(c) Name the main organic product formed when anisole is reacted with Hl.

Text Solution

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A = Tertiary alcohol B = Secondary alcohol C = Primary alcohol
(b) `C_(6)H_(5)COOH + HOC_(6)H_(5) overset(H+)(to) underset("Phenyl Benzoate")(C_(6)H_(5)-COO- C_(6)H_(5)COO) + H_(2)O`
(c) Phenol
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