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Choose the correct statement(s) among th...

Choose the correct statement(s) among the following.

A

`SnCl_(2).2H_(2)O` is reducing agent.

B

`SnO_(2)` reacts with `KOH` to form `K_(2)[Sn(OH)_(6)]`.

C

A solution of `PbCl_(2)` in `HCl` contains `Pb^(2+) and Cl^(-)` ions.

D

The reaction of `Pb_(3)O_(4)` with hot dilute nitric acid to give `PbO_(2)` is a redox reaction.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of choosing the correct statements among the given options, we will analyze each statement step by step. ### Step 1: Analyze the first statement **Statement 1:** SnCl2 is a reducing agent. - **Explanation:** SnCl2 can be oxidized to Sn4+ while reducing another species. Therefore, it acts as a good reducing agent. - **Conclusion:** This statement is **correct**. ### Step 2: Analyze the second statement **Statement 2:** SnO2 reacts with KOH to form K2SnOS6. - **Explanation:** SnO2 is an amphoteric oxide and can react with bases like KOH to form complex ions. The reaction leads to the formation of a complex compound. - **Conclusion:** This statement is **correct**. ### Step 3: Analyze the third statement **Statement 3:** A solution of PbCl2 in HCl contains PbCl2+ and Cl-. - **Explanation:** PbCl2 can form complex ions in the presence of HCl, such as PbCl4^2-. This means that it does not exist simply as Pb2+ and Cl- in solution due to complex formation. - **Conclusion:** This statement is **incorrect**. ### Step 4: Analyze the fourth statement **Statement 4:** The reaction of Pb3O4 with hot dilute nitric acid is a redox reaction. - **Explanation:** When Pb3O4 reacts with dilute nitric acid, it primarily undergoes acid-base reactions rather than a redox reaction. The products do not involve a change in oxidation states. - **Conclusion:** This statement is **incorrect**. ### Final Conclusion The correct statements are: - Statement 1: SnCl2 is a reducing agent (Correct) - Statement 2: SnO2 reacts with KOH to form K2SnOS6 (Correct) - Statement 3: A solution of PbCl2 in HCl contains PbCl2+ and Cl- (Incorrect) - Statement 4: The reaction of Pb3O4 with hot dilute nitric acid is a redox reaction (Incorrect) Thus, the correct options are **A and B**. ---

To solve the problem of choosing the correct statements among the given options, we will analyze each statement step by step. ### Step 1: Analyze the first statement **Statement 1:** SnCl2 is a reducing agent. - **Explanation:** SnCl2 can be oxidized to Sn4+ while reducing another species. Therefore, it acts as a good reducing agent. - **Conclusion:** This statement is **correct**. ...
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