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For a real gas with very large value of ...

For a real gas with very large value of molar volume, which of the following equation can most suitably be applied:
(A) Z = 1 -`(a)/(V_(m)RT)`
(B) PV =RT
(C) Z = 1+ `(Pb)/(RT)`
(D) `PV_(m)`-RT = `(a)/(V_(m)`

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