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Use Hund's rule to derive the electronic...

Use Hund's rule to derive the electronic configuration of `Ce^(3+)` ion and calculate its magnetic moment on the basis of 'spin-only' formula.

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Electronic configuration of multielectron atoms can be written by the use of four quantum numbers and also by following certain principles. Pauli's exclusio principle suggests that maximum capacity of an atomic orbital is two. Auf bau principle suggests that the lower energy orbitals are filled first and hence stability can be attained. Hunds rule of maximum multiplicity suggests that pairing occurs with one electron. The arrangement of electrons in the space around the nucleus can be understood only after writing the electronic configuration. Thus writing electronic configuration is more important in the structure of an atom. Applying Hunds rule of maximum multiplicity, the maximum number of electrons that can posses spin quantum number +1/2 in 4p orbitals is

Electronic configuration of multielectron atoms can be written by the use of four quantum numbers and also by following certain principles. Pauli's exclusion principle suggests that maximum capacity of an atomic orbital is two. Auf bau principle suggests that the lower energy orbitals are filled first and hence stability can be attained. Hunds rule of maximum multiplicity suggests that pairing occurs with one electron. The arrangement of electrons in the space around the nucleus can be understood only after writing the electronic configuration. Thus writing electronic configuration is more important in the structure of an atom. The set of quantum numbers not possible for electrons present in potassium atom in its ground state

Electronic configuration of multielectron atoms can be written by the use of four quantum numbers and also by following certain principles. Pauli's exclusion principle suggests that maximum capacity of an atomic orbital is two. Auf bau principle suggests that the lower energy orbitals are filled first and hence stability can be attained. Hunds rule of maximum multiplicity suggests that pairing occurs with one electron. The arrangement of electrons in the space around the nucleus can be understood only after writing the electronic configuration. Thus writing electronic configuration is more important in the structure of an atom. Auf-bau principle is first violated for the element with atomic numbers

NCERT TELUGU-THE D - ANd F - BLOCK ELEMENTS-Exercises
  1. Compare the stability of + 2 oxidation state of the elements of the fi...

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  2. Compare the chemistry of the actinoids with that of lanthanoids with r...

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  3. How would you account for the following: (i) Of the d^(4) species, ...

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  4. What is meant by 'disproportionation' ? Give an example of disproporti...

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  5. Which metal in the first series of transition metals exhibits + 1 oxid...

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  6. Calculate the number of unpaired electrons in the following gaseous io...

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  7. Give examples and suggest reasons for the following features of the t...

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  8. Indicate the steps in the preparation of: (i) K(2)Cr(2)O(7) from chr...

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  9. What are alloys? Name an important alloy which contains some of the la...

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  10. What are inner transition elements? Decide which of the following atom...

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  11. The chemistry of the actinoid elements is not so smooth as that of the...

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  12. Which is the last element in the series of the actinoids? Write the el...

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  13. Use Hund's rule to derive the electronic configuration of Ce^(3+) ion ...

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  14. Name a member of the lanthanoid senes which is well known to exhibit +...

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  15. Compare the chemistry of the actinoids with that of lanthanoids with r...

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  16. Write the electronic configurations of the elements with the atomic nu...

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  17. Compare the general characteristics of the first series of the transit...

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  18. Write down the number of 3d electrons in each of the following ions : ...

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  19. Comment on the statement that elements of the first transition series ...

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  20. What can be inferred from the magnetic moment values of the following ...

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