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Write structural formulas and names of four possible aldol condensation products from propanal and butanal. In each case, indicate which aldehyde acts as nucleophile and which as electrophile.

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Write the structural formulas and IUPAC names for all possible isomers having the number of double or triple bond as indicated: C_(4)H_(8) (one double bond)

Write the structural formulas and IUPAC names for all possible isomers having the number of double or triple bond as indicated: C_(2)H_(5) (one triple bond)

Write the structural formulas and IUPAC names for all possible isomers having the number of double or triple bond as indicated: C_(5)H_(12) (no multiple bond)

Write the structural formula and IUPAC names for all possible isomers having the number of double or triple bond as indicated : 1) C_(4)H_(8) (one double bond) 2) C_(5)H_(8) (one triple bond) 3) C_(5)H_(12) (no multiple bond)

The products of bond breaking, shown below, are not stable, and cannot be isolated for prolonged study. Such species are referred to as reactive intermediate, and are belived to be transient intermediates in many reactions. The general structures and names of four such intermediates are, Charged Intermediates Uncharged Intermediates Carbocations (called carbonium ions in the older literature) are electrophiles and carbananions are nucleophiles. Carbenes have only a valence shell sextet of electrons and are therefore electron deficient. In this sense they are elecrophiles, but the non-bonding electron pair also gives carbenes nucleophilic character. As a rule, the electrophilic character dominates carbene reactivity. Carbon radicals have only seven valence electrons, and may be considered electron deficient, however, they do not in general bond to nucleophilic electron pair, so their chemistry exhibits differences from that of conventional electrophiles. Radical intermediates are often called free radicals. Intermediates are in general stabilised with conjugation, electron donating and electron with drawing groups. Which of the following is relatively an unstable intermediate compared to rest ?

The products of bond breaking, shown below, are not stable, and cannot be isolated for prolonged study. Such species are referred to as reactive intermediate, and are belived to be transient intermediates in many reactions. The general structures and names of four such intermediates are, Charged Intermediates Uncharged Intermediates Carbocations (called carbonium ions in the older literature) are electrophiles and carbananions are nucleophiles. Carbenes have only a valence shell sextet of electrons and are therefore electron deficient. In this sense they are elecrophiles, but the non-bonding electron pair also gives carbenes nucleophilic character. As a rule, the electrophilic character dominates carbene reactivity. Carbon radicals have only seven valence electrons, and may be considered electron deficient, however, they do not in general bond to nucleophilic electron pair, so their chemistry exhibits differences from that of conventional electrophiles. Radical intermediates are often called free radicals. Intermediates are in general stabilised with conjugation, electron donating and electron with drawing groups. Which of the following carbo cations is more stable?

The products of bond breaking, shown below, are not stable, and cannot be isolated for prolonged study. Such species are referred to as reactive intermediate, and are belived to be transient intermediates in many reactions. The general structures and names of four such intermediates are, Charged Intermediates Uncharged Intermediates Carbocations (called carbonium ions in the older literature) are electrophiles and carbananions are nucleophiles. Carbenes have only a valence shell sextet of electrons and are therefore electron deficient. In this sense they are elecrophiles, but the non-bonding electron pair also gives carbenes nucleophilic character. As a rule, the electrophilic character dominates carbene reactivity. Carbon radicals have only seven valence electrons, and may be considered electron deficient, however, they do not in general bond to nucleophilic electron pair, so their chemistry exhibits differences from that of conventional electrophiles. Radical intermediates are often called free radicals. Intermediates are in general stabilised with conjugation, electron donating and electron with drawing groups. R-N^(+) equiv N" "Cl^(-) rarr R^(+)+N_(2)+Cl^(-) based on the above, which of the following from R^(+) most readily

NCERT TELUGU-ALDEHYDES, KETONES AND CARBOXYLIC ACIDS-Exercises
  1. What is meant by the following terms ? Give an example of the reaction...

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  2. Name the following compounds according to IUPAC system of nomenclature...

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  3. Draw the structures of the following compounds. {:("(i) 3-Methylbuta...

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  4. Write the IUPAC names of the following ketones and aldehydes. Wherever...

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  5. Draw structures of the following derivatives. (i) The 2,4-dinitrophe...

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  6. Predict the products formed when cyclohexanecarbaldehyde reacts with f...

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  7. Which of the following compounds would undergo aldol condensation, whi...

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  8. How will you convert ethanal into the following compounds? (i) Butan...

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  9. Write structural formulas and names of four possible aldol condensatio...

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  10. An organic compound with the molecular formula C(9)H(10)O forms 2,4-DN...

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  11. An organic compound (A) (molecular formula C8H16O2) was hydrolysed wit...

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  12. Arrange the following compounds in increasing order of their property ...

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  13. Give simple chemical tests to distinguish between the following pairs ...

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  14. How will you prepare the following compounds from benzene? You may use...

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  15. Describe the following: (i) Acetylation (ii) Cannizzaro reaction ...

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  16. Complete each synthesis by giving missing starting material, reagent o...

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  17. Give plausible explanation for each of the following: (i) Cyclohexan...

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  18. An organic compound contains 69.77% carbon, 11.63% hydrogen and rest o...

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  19. Although phenoxide ion has more number of resonating structures than c...

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