Why cannot aromatic primary amines be prepared by Gabriel phthalimide synthesis ?

What is Gabriel phthalimide synthesis ?

Aromatic amines can not be prepared by Gabriel phthalimide method. Justiry

Primary amine acts as

Explain the following: a) why the boiling points of primary amines are higher than those of the corresponding tertiary amines of similar molar mass. b) why aromatic amines are lesser basic than aliphatic amines ? c) why alcohols are more acidic than amines of comparable molar mass? d) Gabriel phthalimide synthesis is not useful in the preparation of aromatic primary amines?

How many of the following amines are prepared by Gabrielpthalamide reaction.

Write short notes on (i) Hoffmann bromamide reaction (ii) Gabriel phthalimide synthesis and (iii) Ammonolysis

On reduction , primary amine is formed by

Ketones cannot be prepared by

Primary amines have lower boiling points than