Home
Class 11
CHEMISTRY
A buffer solution is prepared in which t...

A buffer solution is prepared in which the concentration of `NH_(3)` is `0.30 M` and the concentration of `NH_(4)^(+)` is `0.20 M`. If the equilibrium constant, `K_(b)` for `NH_(3)` equals `1.8xx10^(-5)`, what is the `pH` of this solution? (`log 2.7=0.43`)

A

8.73

B

9.08

C

9.43

D

11.72

Text Solution

Verified by Experts

The correct Answer is:
C

`pOH=pK_(a)+"log"(["Conjugate acid"])/(["base"])`
`=-log+1.8x10^(-5)+"log"(0.2)/(0.3)`
`=4.744-0.176=4.567`
`:.pH=14-4.567=9.432`
Promotional Banner

Topper's Solved these Questions

  • ACIDS & BASES

    NARAYNA|Exercise EXERCISE-II (H.W.) (SOLUBILITY PRODUCT & COMMON ION EFFECT)|18 Videos
  • 14TH GROUP ELEMENTS

    NARAYNA|Exercise Subjective Questions|6 Videos
  • ALKANES

    NARAYNA|Exercise Integer Answer Type|7 Videos

Similar Questions

Explore conceptually related problems

A buffer solution is prepared in which the concentration of NH_(3) is 0.30M and the concentration of NH_(4)^(+) is 0.20M . If the equilibrium constant k_(b) for NH_(3) equals 1.8xx10^(-3) what is the pH of this solution?

Calculate the pH of 0.10 M solution of Nh_(4)Cl. The dissociation constant (K_(b)) of NH_(3) is 1.8xx10^(-5)

Calculate the pH of 0.10 M solution of NH_4CI . The dissociation constant (K_b) "of" NH_3 "is" 1.8 xx 10^(-5) .

A basic buffer contains 0.8 mole of NH_(4)Cl and 0.2 mole of NH_(4)OH for litre of a solution the K_(b) of base is 1.8 xx 10^(-5) . Then the P^(H) of the buffer solution is (log 1.8 = 0.2553)

Concentration of NH_(4)Cl and NH_(4)OH in a buffer solution are in the ratio of 1 : 10 , Kb for NH_(4)OH is 10^(-10) . The pH of the buffer is

Calculate [OH^(-)] in 0.20M solution of NH_(3) , if K_(b) for NH_(3) is 1.8xx10^(-5) .

If the concentration of [NH_(4)^(+)] in a solution having 0.02 M NH_(3) and 0.005 M Ca ( OH)_(2) is a xx 10^(-6) M,determine a. [k_(b) ( NH_(3)) = 1.8 xx 10^(-5) ]

NARAYNA-ACIDS & BASES-EXERCISE-III
  1. The ionization constant of ammonium hydroxide is 1.77xx10^(-5) at 298 ...

    Text Solution

    |

  2. The dissociation constants for acetic acid and HCN at 25^(@)C are 1.5x...

    Text Solution

    |

  3. Which of the following molecular hydride act as a Lewis acid ?

    Text Solution

    |

  4. Which of the following describes correct sequence for decreasing Lewis...

    Text Solution

    |

  5. What is [H^(+)] in mol//L of a solution that is 0.20 M in CH(3)COONa a...

    Text Solution

    |

  6. In a buffer solution containing equal concentration of B^(-) and HB, t...

    Text Solution

    |

  7. A buffer solution is prepared in which the concentration of NH(3) is 0...

    Text Solution

    |

  8. Which of the following is least likely to behave as Lew is acid?

    Text Solution

    |

  9. Buffer solutions have constant acidity and alkalinity because

    Text Solution

    |

  10. pH of saturated solution of Ba(OH)(2) is 12. The value of solubility p...

    Text Solution

    |

  11. Equimolar solutions of the following substances were prepared separate...

    Text Solution

    |

  12. In which of the following arrangements the given sequence is not stric...

    Text Solution

    |

  13. Which is the strongest acid in the following ?

    Text Solution

    |

  14. Indentify the correct order of solubility in aqueous medium

    Text Solution

    |

  15. Which of these is least likely to act as Lewis base?

    Text Solution

    |

  16. Which of the following salts will give highest pH in water?

    Text Solution

    |

  17. Using the Gibbs energy change, Delta G^(@)=+ 63.3 kJ, for the followin...

    Text Solution

    |

  18. The K(sp) of Ag(2)CrO(4),AgCl,AgBr and AgI are respectively, 1.1xx10^(...

    Text Solution

    |

  19. Which one of the following pairs of solution is not an acidic buffer?

    Text Solution

    |

  20. What is the pH of the resulting solution when equal volumes of 0.1 M N...

    Text Solution

    |