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Buffer solutions have constant acidity a...

Buffer solutions have constant acidity and alkalinity because

A

they have large excess of `H^(+)` of `OH^(-)` ions

B

they have fixed value of pH

C

these give unionized acid or base on reaction with added acid or alkali

D

acids and alkalies in these solutions are shielded from attack by other ions

Text Solution

Verified by Experts

The correct Answer is:
C

Consider a buffer of `CH_(3)COOH+CH_(3)+COONa`
Addition of acid `: H^(+)+CH_(3)COO^(-) to CH_(3)COOH`
Weak acid
Addition of alkali
`OH^(-)+CH_(3)COOH to H_(2)O+CH_(2)COO^(-)`
Weak electrolyte)
The the additin of acid of alkali does not cause any change in pH,
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NARAYNA-ACIDS & BASES-EXERCISE-III
  1. The ionization constant of ammonium hydroxide is 1.77xx10^(-5) at 298 ...

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  2. The dissociation constants for acetic acid and HCN at 25^(@)C are 1.5x...

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  3. Which of the following molecular hydride act as a Lewis acid ?

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  4. Which of the following describes correct sequence for decreasing Lewis...

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  5. What is [H^(+)] in mol//L of a solution that is 0.20 M in CH(3)COONa a...

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  6. In a buffer solution containing equal concentration of B^(-) and HB, t...

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  7. A buffer solution is prepared in which the concentration of NH(3) is 0...

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  8. Which of the following is least likely to behave as Lew is acid?

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  9. Buffer solutions have constant acidity and alkalinity because

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  10. pH of saturated solution of Ba(OH)(2) is 12. The value of solubility p...

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  11. Equimolar solutions of the following substances were prepared separate...

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  12. In which of the following arrangements the given sequence is not stric...

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  13. Which is the strongest acid in the following ?

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  14. Indentify the correct order of solubility in aqueous medium

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  15. Which of these is least likely to act as Lewis base?

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  16. Which of the following salts will give highest pH in water?

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  17. Using the Gibbs energy change, Delta G^(@)=+ 63.3 kJ, for the followin...

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  18. The K(sp) of Ag(2)CrO(4),AgCl,AgBr and AgI are respectively, 1.1xx10^(...

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  19. Which one of the following pairs of solution is not an acidic buffer?

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  20. What is the pH of the resulting solution when equal volumes of 0.1 M N...

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