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Balance the redox reaction by half react...

Balance the redox reaction by half reaction method :
`Br_(2)+ H_(2)O_(2) to BrO_(3)^(-) + H_(2)O` (in acidic medium)

Text Solution

Verified by Experts

Step -(i) .
(ii) `Br_(2) to 2BrO_(3)^(-) ("oxidation half")`
`H_(2)O_(2) to 2H_(2)O ("Reduction half")`
Oxidation half
`Br_(2) to 2BrO_(3)^(-) +10e^(-)`
`Br_(2)+6H_(2)O to 2BrO_(3)^(-)+10e^(-) ("Balancing oxygen")`
`Br_(2)+6H_(2)O to 2BrO_(3)^(-)+10e^(-)+12H^(+)`
(Balancing hydrogen Reduction half)
`H_(2)O_(2) to H_(2)O`
`H_(2)O_(2)+2e^(-) to 2H_(2)O` (Balancing charge and oxygen)
`H_(2)O_(2)+2e^(-)+2H^(+) to 2H_(2)O`
(Balancing hydrogen Balancing total charge)
(iii) `[Br_(2)+6H_(2)O to 2BrO_(3)^(-)+12H^(+) +10e] xx 1`
`[H_(2)O_(2)+2H^(+)+2e^(-) to 2H_(2)O] xx 5`
`Br_(2)+5H_(2)O+10H^(+) +10e^(-)+6H_(2)O to 2BrO_(3)^(-)+12H^(+)+10e^(-) +10H_(2)O`
Now, we get
`Br_(2)+5H_(2)O to 2BrO_(3)^(-)+4H_(2)O+2H^(+)`
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NARAYNA-REDOX REACTION-Exercise -4
  1. Balance the redox reaction by half reaction method : Br(2)+ H(2)O(2...

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  2. Which of the following represents a redox reaction?

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  3. In the reaction SO(2)+2H(2)Srarr3S+2H(2)O the substance oxidised i...

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  4. In the reaction 3Cl(2)+6NaOHrarrNaClO(3)+5NaCl+3H(2)O the element ...

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  5. The oxidation number of oxygen in OF(2) is

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  6. An oxidation process involves

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  7. Which of the following is the strongest reducing agent in aqueous medi...

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  8. Which of the following is the strongest oxidising agent?

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  9. The oxidation number of phosphorus in Ba(H(2)PO(2))(2) is:-

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  10. Which of the following reactions do not involve oxidation reduction ? ...

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  11. For the redox reaction MnO(4)^(ө)+C(2)O(4)^(2-)+H^(o+)rarrMn^(2+)+CO...

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  12. The oxidation state of nitrogen is correctly given for

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  13. The oxidation state of chromium in Cr(CO)(6) is

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  14. Which of the following is not a redox reaction?

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  15. In the chemical reaction, K(2)Cr(2)O(7)+xH(2)SO(4)+ySO(2)rarrK(2)SO(...

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  16. One mole of N(2)H(4) loses ten moles of electrons of form a new compou...

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  17. When copper is treated with a certain concentration of nitric acid, ni...

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  18. In which of the following pairs is there the greatest difference in th...

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  19. In the reaction 3Br(2) + 6CO(3)^(2-) + 3H(2)O to 5Br^(-) + 2BrO(3)^(...

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  20. In the reaction 2FeCl(3)+H(2)Srarr2FeCl(2)+2HCl+S

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  21. The oxidation number of cobalt in K[Co(CO)(4)] is:

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