Home
Class 12
CHEMISTRY
The correct relation for radius of atom ...

The correct relation for radius of atom and edge length in case of FCC arragement is

A

`r = a/2`

B

`r = (sqrt3a)/(4) `

C

`r = (a)/(2 sqrt 2)`

D

`r = (4a)/(sqrt3)`

Text Solution

AI Generated Solution

The correct Answer is:
To find the correct relation for the radius of an atom (R) and the edge length (A) in a face-centered cubic (FCC) arrangement, we can follow these steps: ### Step-by-Step Solution: 1. **Understanding FCC Structure**: - In a face-centered cubic (FCC) arrangement, atoms are located at each of the eight corners of the cube and at the center of each of the six faces. 2. **Identifying Atomic Touching Points**: - In the FCC structure, the atoms at the corners and the face-centered atoms touch each other along the face diagonal of the cube. 3. **Calculating the Face Diagonal**: - The length of the face diagonal (d) can be calculated using the Pythagorean theorem. Since the face diagonal forms a right triangle with two edges of the cube: \[ d = \sqrt{A^2 + A^2} = \sqrt{2A^2} = A\sqrt{2} \] 4. **Relating the Face Diagonal to Atomic Radii**: - Along the face diagonal, there are three atomic radii (R) involved: one from the corner atom, one from the face-centered atom, and another from the corner atom on the opposite side. Therefore, we can express this as: \[ d = R + 2R + R = 4R \] 5. **Setting Up the Equation**: - Now, we can equate the two expressions for the face diagonal: \[ A\sqrt{2} = 4R \] 6. **Solving for Radius (R)**: - Rearranging the equation to solve for R gives: \[ R = \frac{A\sqrt{2}}{4} \] - This can be simplified to: \[ R = \frac{A}{2\sqrt{2}} \] ### Final Relation: Thus, the correct relation for the radius of an atom (R) and the edge length (A) in the case of a face-centered cubic arrangement is: \[ R = \frac{A}{2\sqrt{2}} \]
Promotional Banner

Topper's Solved these Questions

  • SOLID STATES

    NARAYNA|Exercise EVALUATE YOURSELF - III|5 Videos
  • SOLID STATES

    NARAYNA|Exercise CUQ (INTRODUCTION)|2 Videos
  • SOLID STATES

    NARAYNA|Exercise EVALUATE YOURSELF - I|6 Videos
  • QUALITATIVE ANALYSIS

    NARAYNA|Exercise Subjective Type Question|33 Videos
  • SOLUTIONS & COLLIGATIVE PROPERTIES

    NARAYNA|Exercise EXERCISE : 4|26 Videos

Similar Questions

Explore conceptually related problems

The correct relation for radius of atom and edge - length in case of fcc arrangement is

In the face-centred cubic unit cell of cloest packed atom,s the radius of atoms of edge length (a) of the unit cell is

In the primitie cubic unit cell of closed packed atoms, the radius of atom in terms of edge length (a) of unit cell is

The relation between atomic radius and edge length 'a' of a body centred cubic unit cell :

Express the relation between atomic radius (r) and edge length (a) in b.c.c. unit cell.

Atomic radius of fcc is

In a face centred cubic unit cell of close packed atoms, the radius of atom (r) is related to the edge length (a) of the unit cell by the expression

The relation between atomic radius (r ) and the edge (a) of the unit cell are given below. Which is correctly matched.