Home
Class 12
CHEMISTRY
Any deviation from the perfectly ordered...

Any deviation from the perfectly ordered arrangement constitutes a defect or imperfection. The compounds in which the number of irregularity are present in the arrangement of atoms or ions are called atomic imperfections or point defects. These may be stochiometric or non - stoichlometric. Stoichiometric defects are further classified into Schottky defects in which number of positive and negative ions are missing in equal ratio and Frenkel defects in which an ion leaves its correct lattice sites and occupies on interstitial site. Schottky defect is more common in ionic compounds with high co-ordination number and where the size of positive and negative ions are almost equal, while in Frenkel defects are common in ionic compounds, which have low co-ordination number and in which there is large difference in size between positive and negative ions.
When an ion leaves ir correct lattice and occupies interstital sites in its crystal lattice, it is called

A

Frenkel defect

B

Schottky defect

C

impurity defect

D

vacancy defect

Text Solution

Verified by Experts

The correct Answer is:
A
Promotional Banner

Topper's Solved these Questions

  • SOLID STATES

    NARAYNA|Exercise EXERCISE-4|18 Videos
  • SOLID STATES

    NARAYNA|Exercise EXERCISE-2 (H.W) (MATRIX MATCHING TYPE )|2 Videos
  • QUALITATIVE ANALYSIS

    NARAYNA|Exercise Subjective Type Question|33 Videos
  • SOLUTIONS & COLLIGATIVE PROPERTIES

    NARAYNA|Exercise EXERCISE : 4|26 Videos

Similar Questions

Explore conceptually related problems

Any deviation from the perfectly ordered arrangement constitutes a defect or imperfection. The compounds in which the number of irregularity are present in the arrangement of atoms or ions are called atomic imperfections or point defects. These may be stochiometric or non - stoichlometric. Stoichiometric defects are further classified into Schottky defects in which number of positive and negative ions are missing in equal ratio and Frenkel defects in which an ion leaves its correct lattice sites and occupies on interstitial site. Schottky defect is more common in ionic compounds with high co-ordination number and where the size of positive and negative ions are almost equal, while in Frenkel defects are common in ionic compounds, which have low co-ordination number and in which there is large difference in size between positive and negative ions. KBr shows, which of the following stoichiometric defects ?

Any deviation from the perfectly ordered arrangement constitutes a defect or imperfection. The compounds in which the number of irregularity are present in the arrangement of atoms or ions are called atomic imperfections or point defects. These may be stochiometric or non - stoichlometric. Stoichiometric defects are further classified into Schottky defects in which number of positive and negative ions are missing in equal ratio and Frenkel defects in which an ion leaves its correct lattice sites and occupies on interstitial site. Schottky defect is more common in ionic compounds with high co-ordination number and where the size of positive and negative ions are almost equal, while in Frenkel defects are common in ionic compounds, which have low co-ordination number and in which there is large difference in size between positive and negative ions. Which of the following defect, if present, lowers the density of the crystal ?

Any deviation from the perfectly ordered arrangement constitutes a defect or imperfection. The compounds in which the number of irregularity are present in the arrangement of atoms or ions are called atomic imperfections or point defects. These may be stochiometric or non - stoichlometric. Stoichiometric defects are further classified into Schottky defects in which number of positive and negative ions are missing in equal ratio and Frenkel defects in which an ion leaves its correct lattice sites and occupies on interstitial site. Schottky defect is more common in ionic compounds with high co-ordination number and where the size of positive and negative ions are almost equal, while in Frenkel defects are common in ionic compounds, which have low co-ordination number and in which there is large difference in size between positive and negative ions. In a crystal some ions are missing from normal sites. This is an example of

Non-Stoichiometric defect

Which has Frenkel defect ?

Frenkel and Schottky defects are:

Why stoichiometric defects are also called intrinsic defects?

NARAYNA-SOLID STATES-EXERCISE-3
  1. Atomic radius of Ag is similar to

    Text Solution

    |

  2. The fraction of total volume occupied by the atom present in a simple ...

    Text Solution

    |

  3. Any deviation from the perfectly ordered arrangement constitutes a def...

    Text Solution

    |

  4. Which of the following statement is not correct?

    Text Solution

    |

  5. The number of atoms in a cubic based unit cell having one atom on each...

    Text Solution

    |

  6. In a closed packed structure

    Text Solution

    |

  7. Oxidation states of X,Y,Z are +2,+5 and -2 respectively. Formula of th...

    Text Solution

    |

  8. Schottky defect to crystals is observed when

    Text Solution

    |

  9. The edge length of a cube is 400 pm .its body diagonal would be

    Text Solution

    |

  10. Assertion :No compound has both schottky and frenkel defect Reason ...

    Text Solution

    |

  11. With Which one of the following elements silicon should be doped so as...

    Text Solution

    |

  12. The percentage of free space in a body centred cubic unit cell is

    Text Solution

    |

  13. If 'a' stands for the edge length of the cubic systems: simple cubic,b...

    Text Solution

    |

  14. The structure of TICI is silmilar to CsCI .What would be the radius r...

    Text Solution

    |

  15. The maximum number of Bravais lattices is shown by tetragonal-type cry...

    Text Solution

    |

  16. Which property makes the crystalline solids to have sharp melting poin...

    Text Solution

    |

  17. Sodium crystallises in bcc arrangement with the interfacial separation...

    Text Solution

    |

  18. Lithium metal crystallizes in a body centred cubic crystals. If the le...

    Text Solution

    |

  19. Copper crystallises in face-centred cubic lattice with a unit cell len...

    Text Solution

    |

  20. In Na2O, having antifluorite structure

    Text Solution

    |