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Ionic radii of Mg^(2+) and O^(2-) ions a...

Ionic radii of `Mg^(2+)` and `O^(2-)` ions are 66pm and 140pm respectively. The type of intersitital void and coordination number of `Mg^(2+)` ion respectively are

A

tetrahcdral, 12

B

octahedral, 6

C

tetrahedral, 6

D

octahedral, 8

Text Solution

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The correct Answer is:
A

Radius ratio `(r_(mg^(+2)) )/(r_(O^(2-) )) = 66/140 = 0.47`
Hence `Mg^(2+)` occupies octahedral void
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NARAYNA-SOLID STATES-EXERCISE-4
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