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1) Nitrogen dioxide reacts with hydrogen...

1) Nitrogen dioxide reacts with hydrogen to give nitrogen and water according to the equation:
`2NO_(2) + H_(2) to N_(2) + H_(2)O_(2)` (slow)
`H_(2) + H_(2)O_(2) to 2H_(2)O` (fast)
What is the predicted rate law?
(1) Rate `=K[NO_(2)]`,
(2) Rate `=K[H_(2)]^(2)`
(3) Rate `=K[NO_(2)]^(2) [H_(2)]`
(4) Rate `=K[NO_(2)][H_(2)]`

Text Solution

AI Generated Solution

To determine the predicted rate law for the given reaction mechanism, we will analyze the steps involved in the reaction. ### Step 1: Identify the Rate-Determining Step The reaction consists of two steps: 1. **Slow Step**: \( 2NO_2 + H_2 \rightarrow N_2 + H_2O_2 \) 2. **Fast Step**: \( H_2 + H_2O_2 \rightarrow 2H_2O \) In chemical kinetics, the rate law is determined by the slowest step of the reaction, known as the rate-determining step. This is because the slow step will dictate the overall rate of the reaction. ...
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NARAYNA-CHEMICAL KINETICS -EXERCISE -4
  1. 1) Nitrogen dioxide reacts with hydrogen to give nitrogen and water ac...

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  2. The role of a catalyst is to change

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  3. In the presence of a catalyst, the heat evolved or absorbed during the...

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  4. Activation energy of a chemical reaction can be determined by:

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  5. Consider figure and mark the correct option

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  6. Consider a first order gas phase decomposition reaction given below: ...

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  7. According to Arrhenius equation rate constant K is equal to A e.^(-...

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  8. Consider the Arrhenius equation given below and mark the correct op...

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  9. Which of the following statement is not correct about order of a ...

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  10. Consider the graph given in figure . Which of the following optio...

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  11. Which of the following statements is correct?

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  12. Which of the following expression is correct for the rate of reac...

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  13. Rate law for the reaction, A + 2B to C is found to be Rate = k [A] [...

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  14. Which of the following statements is incorrect about the collison theo...

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  15. A first order reaction is 50% completed in 1.26 xx 10^(14)s. How much ...

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  16. Which of the following statements is not correct for the catalyst?

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  17. The value of rate constant of a pseudo first order reaction

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  18. Consider the reaction A to B. The concentration of both the reactan...

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  19. The time for half-life period of a certain reaction, A rarr products i...

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  20. The rate of a chemical reaction doubles for every 10^(@)C rise of temp...

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  21. A reactant (A) forms two products A overset(K(1)) to B, Activation en...

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