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The reaction that obeys the expression t...

The reaction that obeys the expression `t_(1/2) = 1/(Ka)` the order of reaction

A

0

B

1

C

2

D

3

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To determine the order of the reaction given the expression for half-life \( t_{1/2} = \frac{1}{k_a} \), we will analyze the relationship between the half-life and the rate constant for different orders of reactions. ### Step-by-Step Solution: 1. **Understanding Half-Life Expressions**: - The half-life of a reaction is the time required for the concentration of a reactant to reduce to half its initial value. The expression for half-life varies depending on the order of the reaction. 2. **General Expression for Half-Life**: - For different orders of reactions, the half-life expressions are: - **Zero-order reaction**: \[ t_{1/2} = \frac{[A]_0}{2k} \] - **First-order reaction**: \[ t_{1/2} = \frac{0.693}{k} \] - **Second-order reaction**: \[ t_{1/2} = \frac{1}{k[A]_0} \] 3. **Comparing Given Expression**: - The given expression is \( t_{1/2} = \frac{1}{k_a} \). This expression does not include the concentration of the reactant \( [A] \). 4. **Testing Different Orders**: - **Zero-order**: The half-life depends on the initial concentration, so it cannot be equal to \( \frac{1}{k_a} \). - **First-order**: The half-life is independent of concentration but is expressed as \( \frac{0.693}{k} \), which does not match the given expression. - **Second-order**: The half-life is given by \( t_{1/2} = \frac{1}{k[A]_0} \), which indicates that it depends on the initial concentration. However, if we consider the scenario where the concentration is constant or not specified, we can simplify to \( t_{1/2} = \frac{1}{k} \) when we assume \( [A]_0 = 1 \). 5. **Conclusion**: - The only scenario where \( t_{1/2} = \frac{1}{k_a} \) holds true without any concentration dependence is for a second-order reaction when we assume a specific initial concentration. Thus, the order of the reaction is **second order**. ### Final Answer: The order of the reaction is **second order**.

To determine the order of the reaction given the expression for half-life \( t_{1/2} = \frac{1}{k_a} \), we will analyze the relationship between the half-life and the rate constant for different orders of reactions. ### Step-by-Step Solution: 1. **Understanding Half-Life Expressions**: - The half-life of a reaction is the time required for the concentration of a reactant to reduce to half its initial value. The expression for half-life varies depending on the order of the reaction. 2. **General Expression for Half-Life**: ...
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