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If the rate of reaction A to B triples o...

If the rate of reaction `A to B` triples on increasing the concentration of A by 9 times, then the order of reaction is

A

2

B

1

C

`1/2`

D

4

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of the reaction based on the given information, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Rate Law**: The rate of a reaction can be expressed using the rate law: \[ \text{Rate} = k[A]^n \] where \( k \) is the rate constant, \( [A] \) is the concentration of reactant A, and \( n \) is the order of the reaction. 2. **Initial and New Conditions**: Let the initial concentration of A be \( [A] \) and the initial rate be \( R \): \[ R = k[A]^n \] When the concentration of A is increased by 9 times, the new concentration becomes \( 9[A] \). The new rate \( R' \) is given to be three times the initial rate: \[ R' = 3R \] 3. **Express the New Rate**: The new rate can also be expressed using the rate law: \[ R' = k(9[A])^n = k \cdot 9^n \cdot [A]^n \] 4. **Set Up the Equation**: Now, we can set the two expressions for the new rate equal to each other: \[ 3R = k \cdot 9^n \cdot [A]^n \] Substituting \( R = k[A]^n \) into the equation gives: \[ 3(k[A]^n) = k \cdot 9^n \cdot [A]^n \] 5. **Cancel Common Terms**: We can cancel \( k \) and \( [A]^n \) from both sides (assuming \( [A] \neq 0 \)): \[ 3 = 9^n \] 6. **Rewrite 9 in Terms of 3**: Since \( 9 = 3^2 \), we can rewrite the equation: \[ 3 = (3^2)^n = 3^{2n} \] 7. **Equate Exponents**: Since the bases are the same, we can equate the exponents: \[ 1 = 2n \] 8. **Solve for n**: Dividing both sides by 2 gives: \[ n = \frac{1}{2} \] 9. **Conclusion**: The order of the reaction is \( n = 0.5 \) or \( \frac{1}{2} \). ### Final Answer: The order of the reaction is \( \frac{1}{2} \) or 0.5.

To determine the order of the reaction based on the given information, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Rate Law**: The rate of a reaction can be expressed using the rate law: \[ \text{Rate} = k[A]^n ...
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