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Which of the following is the correct st...

Which of the following is the correct statement

A

Order of a reaction has always an integral value lt

B

Mechanism of a reactional proposed is always final

C

Zero order reactions are multi-step reactions

D

Order of reaction can be predicted even without knowing the rate law

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AI Generated Solution

The correct Answer is:
To solve the question, we need to evaluate each of the four statements provided and determine which one is correct regarding chemical kinetics. ### Step-by-Step Solution: 1. **Evaluate the first statement**: "The order of the reaction is always an integral value." - The order of a reaction is determined experimentally and can be a positive integer, negative integer, or even a fraction. Therefore, this statement is **incorrect**. 2. **Evaluate the second statement**: "The proposed mechanism is always final." - Reaction mechanisms can be proposed based on experimental data, but they are subject to change as new data becomes available. Different mechanisms may be valid under different conditions. Thus, this statement is **incorrect**. 3. **Evaluate the third statement**: "Zero-order reactions are multi-steps." - Zero-order reactions are typically elementary reactions, which means they occur in a single step. Therefore, this statement is **incorrect**. 4. **Evaluate the fourth statement**: "The order of a reaction can be predicted even without knowing the rate law." - The order of a reaction is indeed an experimental quantity that can be determined through experiments without necessarily knowing the rate law. This statement is **correct**. ### Conclusion: The correct statement among the options provided is: **"The order of a reaction can be predicted even without knowing the rate law."**
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NARAYNA-CHEMICAL KINETICS -EXERCISE -3
  1. The rate constant of a first order reaction at 27^@C is 10–3 min–1. Th...

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  2. The concentration of a reactant X decreases from 0.1 M to 0.005 M in 4...

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  3. For a reversible reaction A <implies B , which one of the following st...

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  4. The plote between concentration versus time for a zero order reaction ...

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  5. For the reaction,, 2A + B to C + D, the order of reaction is

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  6. In the reaction BrO^(-3)(aq) + 5Br^(-) (aq) + 6H^(+) rarr 3Br(2)(1) ...

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  7. For the reaction A + B products, it is observed that: (1) on doublin...

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  8. 3BrO^(-) to BrO(3)^(-) + 3Br^(-) If -(d[BrO^(-)])/(dt) = k(1) [BrO^(...

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  9. For a reaction, the dimensions of rate constant are same as that of ra...

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  10. For a first order reaction, the time required for 99.9% of the reactio...

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  11. Rate of the given reaction, (1) A + B overset(r(1)=0.05) to X (2) ...

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  12. Which of the following is the correct statement

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  13. For an endothermic reaction energy of activation is E(a) and enthlpy o...

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  14. The rate of the reaction 2NO+CI(2)rarr 2NOCI is given by the rate ...

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  15. For the reaction N(2)O(5) rarr 2NO(2) + (1)/(2) O(2), the rate of disa...

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  16. Which one of the following statements for the order of a reaction is i...

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  17. The activation energy of a reaction can be determined from the slope o...

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  18. When initial concentration of a reactant is doubled in a reaction, its...

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  19. The rate constant of the reaction A rarr B is 0.6 xx 10^(-3) mole per ...

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  20. The rate of a first-order reaction is 0.04 "mol L"^(-1) s^(-1) at 10 s...

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