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The following is an example of Sandmeyer...

The following is an example of Sandmeyer reaction

A

`C_6H_5N_2^+Cl^(-)overset(CuCl//HCl)rarrC_6H_5Cl`

B

`C_6H_5N_2^+Cl^(-)overset(H_2"O"//Delta)rarrC_6H_5OH`

C

`C_6H_5N_2^+Cl^(-)overset(HBF_4)rarrC_6H_5F`

D

`C_6H_5N_2^+Cl^(-)overset(KI//"warm")rarrC_6H_5I`

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The correct Answer is:
To determine which of the given reactions is an example of the Sandmeyer reaction, we need to understand the key components and conditions of the Sandmeyer reaction. ### Step-by-Step Solution: 1. **Identify the Sandmeyer Reaction**: - The Sandmeyer reaction involves the conversion of an aryl diazonium salt into a haloarene (chlorobenzene or bromobenzene) using cuprous halides (CuX) in the presence of hydrogen halide (HX). 2. **Analyze the Given Options**: - **Option A**: Benzene diazonium chloride reacts with CuCl and HCl to form chlorobenzene. - **Option B**: Benzene diazonium chloride reacts with water and heat to form phenol. - **Option C**: Benzene diazonium chloride reacts with HBF4 to form fluorobenzene. - **Option D**: Benzene diazonium chloride reacts with potassium iodide to form iodobenzene. 3. **Evaluate Each Option**: - **Option A**: This matches the Sandmeyer reaction criteria (CuCl + HCl). Therefore, this is a Sandmeyer reaction. - **Option B**: This involves hydrolysis of the diazonium salt to form phenol, which is not a Sandmeyer reaction. - **Option C**: This uses HBF4 to produce fluorobenzene, which is not part of the Sandmeyer reaction (only Cl and Br are formed). - **Option D**: This uses potassium iodide to produce iodobenzene, which again does not fit the Sandmeyer criteria. 4. **Conclusion**: - The only option that represents a Sandmeyer reaction is **Option A**, where benzene diazonium chloride reacts with CuCl and HCl to yield chlorobenzene. ### Final Answer: **Option A** is the example of the Sandmeyer reaction.

To determine which of the given reactions is an example of the Sandmeyer reaction, we need to understand the key components and conditions of the Sandmeyer reaction. ### Step-by-Step Solution: 1. **Identify the Sandmeyer Reaction**: - The Sandmeyer reaction involves the conversion of an aryl diazonium salt into a haloarene (chlorobenzene or bromobenzene) using cuprous halides (CuX) in the presence of hydrogen halide (HX). 2. **Analyze the Given Options**: ...
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NARAYNA-HALOALKANE AND HALOARENES-EXERCISE - I (H.W)
  1. What is X in the following reaction ? C2H5Cl+XrarrC2H5OH+KCl

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  2. Which of the following acids will give maximum yield of alkyl chloride...

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  3. In the reaction sequence C2H5Cl+KCNoverset(C2H5OH)rarrX What is th...

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  4. Ethyl chloride on heating with AgCN fonns a compound (X ). The functio...

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  5. With Zn - Cu couple and C2H5OH , ethyl Iodide reacts to give

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  6. In the dehydrohalogenation of ethyl chloride the following change occu...

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  7. The reaction C2H5Cl+OH^(-) rarr C2H5OH+Cl^(-) is

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  8. (R ) -2- Octy tosylate is sololyzed in water under ideal S(N^(1)) cond...

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  9. The absolute configuration of a molecule changes during the reaction.

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  10. For a uncleophillic substitution reaction the rate was found in the or...

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  11. SN2 reaction leads to

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  12. Which of the following alkyl halides is hydrolysed by S(N^(1)) mechani...

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  13. Chloro benzene can be prepared by reacting benzene diazonium chloride ...

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  15. The following is an example of Sandmeyer reaction

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  16. Chlorobenzene on reaction with CH3Cl in presence of AlCl3 gives

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  17. 2C6H5Cl+2Na overset(dry ether)rarrX,X is

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  18. Chlorobenzene on fusing with solid NaOH gives

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  19. Chlorobenzene on nitration gives major product of

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  20. The reaction C6H5I+2Na+CH3Ioverset(dry ether) rarrC6H5CH3+2NaI is

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