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During Friedel craft reaction of Benzene...

During Friedel craft reaction of Benzene with `CH_3Cl` in presence of `AlCl_3` find product is

A

B

C

D

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The correct Answer is:
To solve the question regarding the product formed during the Friedel-Crafts reaction of benzene with CH₃Cl in the presence of AlCl₃, we can follow these steps: ### Step 1: Understand the Reaction Type The Friedel-Crafts reaction is an electrophilic aromatic substitution (EAS) reaction. In this reaction, benzene acts as a nucleophile and reacts with an electrophile. **Hint:** Remember that benzene is electron-rich due to its delocalized π electrons, making it susceptible to attack by electrophiles. ### Step 2: Identify the Electrophile In this reaction, CH₃Cl (methyl chloride) is used. In the presence of AlCl₃ (aluminum chloride), which is a Lewis acid, CH₃Cl can generate a methyl cation (CH₃⁺) as the electrophile. **Hint:** A Lewis acid like AlCl₃ can accept electron pairs, facilitating the formation of the electrophile. ### Step 3: Formation of the Methyl Cation When CH₃Cl reacts with AlCl₃, the bond between carbon and chlorine breaks. The chlorine atom takes the bonding electrons, forming a methyl cation (CH₃⁺) and AlCl₄⁻. **Hint:** The more electronegative chlorine pulls the electrons towards itself, leaving a positively charged carbon. ### Step 4: Electrophilic Attack on Benzene The methyl cation (CH₃⁺) acts as the electrophile and attacks the electron-rich benzene ring. This results in the formation of a new carbon-carbon bond, leading to the formation of a carbocation intermediate. **Hint:** The π bond of benzene breaks to form a new bond with the electrophile, creating a temporary positive charge on the benzene ring. ### Step 5: Deprotonation to Form the Final Product To stabilize the carbocation, a hydrogen atom from the benzene ring is removed (deprotonation), resulting in the formation of toluene (C₆H₅CH₃). The hydrogen combines with the AlCl₄⁻ to form HCl and regenerate AlCl₃. **Hint:** The removal of a proton restores aromaticity to the benzene ring and completes the substitution reaction. ### Step 6: Write the Final Products The final products of the reaction are toluene (C₆H₅CH₃) and hydrogen chloride (HCl). The AlCl₃ is regenerated and acts as a catalyst. **Hint:** Catalysts are not consumed in the reaction; they are regenerated at the end. ### Conclusion The product formed during the Friedel-Crafts reaction of benzene with CH₃Cl in the presence of AlCl₃ is toluene (C₆H₅CH₃) and HCl. **Final Answer:** Toluene and HCl.

To solve the question regarding the product formed during the Friedel-Crafts reaction of benzene with CH₃Cl in the presence of AlCl₃, we can follow these steps: ### Step 1: Understand the Reaction Type The Friedel-Crafts reaction is an electrophilic aromatic substitution (EAS) reaction. In this reaction, benzene acts as a nucleophile and reacts with an electrophile. **Hint:** Remember that benzene is electron-rich due to its delocalized π electrons, making it susceptible to attack by electrophiles. ### Step 2: Identify the Electrophile ...
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NARAYNA-HALOALKANE AND HALOARENES-EXERCISE - II (C.W)
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  3. When CH3CH2CHCl2 is treated with NaNH2, the product formed is

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  4. CH(3)CH(2)Cloverset(NaCN)rarrXoverset(Ni//H(2))rarrYunderset("anhydrid...

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  5. Benzene reacts with chlorine to form benzene hexachloride in presence ...

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  6. Chloroform when treated with aniline and alcoholic KOH forms -

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  7. The reaction C2H5ONa+BrC2H5rarrC2H5-O-C2H5+NaBr is called

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  8. Identify Z in the following series: C(2) H(5) I underset("KOH")over...

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  9. What is X in the following reaction ? C2H5Cl +X rarrC2H5OH + KCl

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  10. 1 - Chloroprapane and 2 - chloropropane are

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  11. The compound , pyrene, used in fire extinguishers is

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  12. On sulphonation of C6H5 Cl

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  13. Which is the carbylamine reaction ?

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  14. The product formed in the following reaction is CH3CH(CH3)CH=CH2+HBrra...

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  15. Total number of acyclic isomers including stereoisomers of AlCl3 find ...

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  16. During Friedel craft reaction of Benzene with CH3Cl in presence of AlC...

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  17. Chlorobenzene reacts with Mg in dry ether to give a compound A, which ...

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  19. What is C ?

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  20. The correct orders of reactivity tow ards SN1 reaction is

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