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C2H5OH+SOCl2overset("Pyridine")rarrx+y+z...

`C_2H_5OH+SOCl_2overset("Pyridine")rarrx+y+z` in this reaction x, y and z respectively are

A

`C_2H_4CI_2, SO_2,HCI`

B

`C_2H_5CI,SO_2,HCI`

C

`C_2H_5Cl, SOCl`

D

`C_2H_4,SO_2,Cl_2`

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The correct Answer is:
To solve the reaction of ethanol (C₂H₅OH) with thionyl chloride (SOCl₂) in the presence of pyridine, we can break down the process step by step. ### Step 1: Understanding the Reactants - Ethanol (C₂H₅OH) is an alcohol. - Thionyl chloride (SOCl₂) is a reagent commonly used to convert alcohols into alkyl chlorides. - Pyridine acts as a base in this reaction, helping to facilitate the conversion. ### Step 2: Reaction Mechanism 1. **Proton Abstraction**: Pyridine abstracts a proton (H⁺) from the hydroxyl group (-OH) of ethanol. This forms an ethoxide ion (C₂H₅O⁻) and a pyridinium ion (C₅H₅NH⁺). \[ C_2H_5OH + Pyridine \rightarrow C_2H_5O^- + C_5H_5NH^+ \] 2. **Formation of Alkyl Chloride**: The ethoxide ion then reacts with thionyl chloride. The sulfur atom in SOCl₂ is electrophilic, and it will react with the ethoxide ion to form ethyl chloride (C₂H₅Cl). \[ C_2H_5O^- + SOCl_2 \rightarrow C_2H_5Cl + SO_2 + HCl \] ### Step 3: Products of the Reaction From the above steps, we can identify the products: - **X**: Ethyl chloride (C₂H₅Cl) - **Y**: Sulfur dioxide (SO₂) - **Z**: Hydrogen chloride (HCl) ### Final Answer Thus, in the reaction \( C_2H_5OH + SOCl_2 \overset{\text{Pyridine}}{\rightarrow} x + y + z \), the products are: - **X** = C₂H₅Cl (ethyl chloride) - **Y** = SO₂ (sulfur dioxide) - **Z** = HCl (hydrochloric acid)

To solve the reaction of ethanol (C₂H₅OH) with thionyl chloride (SOCl₂) in the presence of pyridine, we can break down the process step by step. ### Step 1: Understanding the Reactants - Ethanol (C₂H₅OH) is an alcohol. - Thionyl chloride (SOCl₂) is a reagent commonly used to convert alcohols into alkyl chlorides. - Pyridine acts as a base in this reaction, helping to facilitate the conversion. ### Step 2: Reaction Mechanism ...
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NARAYNA-HALOALKANE AND HALOARENES-EXERCISE - II (H.W)
  1. Secondary be akkyl halide among the following is

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  2. RCl+NaI overset("Acetone")rarr R-I+NaCl This reaction is known as

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  3. C2H5OH+SOCl2overset("Pyridine")rarrx+y+z in this reaction x, y and z r...

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  4. 2-Methylbutane on reaction with bromine in the presence of sunlight gi...

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  5. In the Hunsdiecker reaction .

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  6. Complete the following reaction

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  7. Among the following , the compound with highest density is

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  8. C2H5Cl +Ag OH rarrA+AgCl . A+CH3COClrarrA+AgCl. ''C '' is

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  9. The compound (B) in the below reaction is , C2H5Cloverset(KCN)rarrAo...

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  10. Cholor ethane reacts with X to form diethyl ether. What is X ?

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  11. 1- Chlorobutane on reaction with alchloic potash gives:

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  12. Which of the following is correct order of reactivity

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  13. Addition of to the aqueous hydrolysis of benzyl chloride dose not incr...

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  14. The correct order of decreasing SN2 respectively

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  15. Direction iodination of benzene is not possible because

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  16. On treatment of Toluene with CI..in presence of Fe, dark the product f...

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  17. The major mono product in the reaction is X. Identify the product...

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  18. The correct order of increasing boiling points is

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  19. Aryl halides are less reactive towards nucleophilic substitution react...

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  20. Replacement of CI of chloro benzene to give phenol requires drastic co...

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