On treatment of Toluene with CI..in presence of Fe, dark the product formed is

Options

A. o-and p-chloro Toluene
B. benzyl Chloride
C. m-chloro Toluene
D. only p-chloro Toluene

Explanation

To solve the question regarding the treatment of Toluene with Chlorine in the presence of Fe, we can follow these steps:

### Step-by-Step Solution:

1. **Identify the Reactants**:
- We start with Toluene (C7H8), which has a methyl group (-CH3) attached to a benzene ring.

2. **Understand the Reaction Conditions**:
- The reaction involves Chlorine (Cl2) and Iron (Fe) as a catalyst. The presence of Fe indicates that it will facilitate the generation of an electrophile.

3. **Formation of Electrophile**:
- When Chlorine reacts with Iron, it forms Iron(III) chloride (FeCl3), which acts as a Lewis acid. This Lewis acid will interact with Cl2 to generate a chloronium ion (Cl+), which is a strong electrophile.

4. **Electrophilic Aromatic Substitution**:
- Toluene, being an electron-rich aromatic compound due to the presence of the -CH3 group, will undergo electrophilic aromatic substitution. The -CH3 group is an electron-donating group and directs the incoming electrophile (Cl+) to the ortho and para positions of the benzene ring.

5. **Identify the Products**:
- The electrophile (Cl+) will attack the benzene ring at two positions:
- **Ortho Position**: This leads to the formation of ortho-chlorotoluene.
- **Para Position**: This leads to the formation of para-chlorotoluene.

6. **Final Products**:
- The products formed from this reaction are:
- Ortho-chlorotoluene (1-chloro-2-methylbenzene)
- Para-chlorotoluene (1-chloro-4-methylbenzene)

### Conclusion:
The products formed from the treatment of Toluene with Chlorine in the presence of Fe are **Ortho-chlorotoluene and Para-chlorotoluene**.