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When aryl halide are treated with sodium...

When aryl halide are treated with sodium in dry ether , it gives a product in which two aryl group are joined together. This reaction is called as

A

Wurtz reaction

B

Fitting reaction

C

Wurtz's Fitting reaction

D

Swarts reaction

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The correct Answer is:
To solve the question regarding the reaction of aryl halides with sodium in dry ether, we can break it down into the following steps: ### Step 1: Understanding the Reactants We start with aryl halides, which are compounds that contain a halogen atom (like Cl, Br, or I) attached to an aromatic ring. The presence of sodium (Na) and dry ether as a solvent is crucial for the reaction. **Hint:** Identify the structure of aryl halides and the role of sodium and dry ether in the reaction. ### Step 2: Reaction Mechanism When aryl halides are treated with sodium in dry ether, a coupling reaction occurs. Sodium acts as a reducing agent, facilitating the removal of the halogen atom from the aryl halide. This leads to the formation of a radical species. **Hint:** Consider how sodium interacts with the halogen in the aryl halide and the formation of radicals. ### Step 3: Formation of Biphenyl The radicals generated from two aryl halides can then couple together to form a new compound. In this case, two aryl groups combine to form biphenyl, which is a compound consisting of two phenyl rings connected by a single bond. **Hint:** Visualize the coupling of two aryl radicals to form a biphenyl structure. ### Step 4: By-products of the Reaction During this reaction, sodium halide (NaX) is produced as a by-product. Since two aryl halides are used, two moles of sodium halide will be formed. **Hint:** Remember to account for the by-products formed during the reaction. ### Step 5: Naming the Reaction This specific reaction where aryl halides couple in the presence of sodium in dry ether is known as the **Wurtz reaction**. It is a classic method for forming biphenyls from aryl halides. **Hint:** Recall the name associated with the coupling of aryl groups through the use of sodium. ### Final Answer The reaction when aryl halides are treated with sodium in dry ether, resulting in the joining of two aryl groups, is called the **Wurtz reaction**. ---
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