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In the reaction CH3-overset(CH3)overset(...

In the reaction `CH_3-overset(CH_3)overset(|)(CH)-CH(OH)-CH_2-CH_3 +HIoverset("Heated")rarr` compound will be formed ?

A

`CH_3-overset(CH_3)overset(|)(CH)-CH_3OH+CH_3-CH_2-I`

B

`CH_3-overset(CH_3)overset(|)(CH)-CH_3-I+CH_3CH_2OH`

C

`CH_3-underset(CH_3)underset(|)(CH)-CH_3+CH_3CH_2OH`

D

`CH_3-underset(CH_3)underset(|)(CH)-CH_2OH+CH_3CH_2`

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The correct Answer is:
To solve the reaction of the compound \( CH_3-CH(CH_3)-CH(OH)-CH_2-CH_3 \) with HI when heated, we will follow these steps: ### Step 1: Identify the Reactants The reactant is \( CH_3-CH(CH_3)-CH(OH)-CH_2-CH_3 \) and it will react with hydroiodic acid (HI). ### Step 2: Protonation of the Alcohol When HI is added, the hydroxyl group (-OH) will be protonated by the \( H^+ \) from HI. This leads to the formation of water (H2O) and a carbocation. The reaction can be represented as: \[ CH_3-CH(CH_3)-CH(OH)-CH_2-CH_3 + H^+ \rightarrow CH_3-CH(CH_3)-C^+(H_2O)-CH_2-CH_3 \] ### Step 3: Formation of Carbocation The protonation of the -OH group leads to the formation of a better leaving group (water). The resulting carbocation will be: \[ CH_3-CH(CH_3)-C^+-CH_2-CH_3 \] ### Step 4: Carbocation Rearrangement Next, we check the stability of the carbocation. The carbocation can rearrange to form a more stable carbocation by shifting a hydride ion (H-) from the adjacent carbon: \[ CH_3-CH^+(CH_3)-CH_2-CH_3 \rightarrow CH_3-CH_2-CH^+(CH_3)-CH_3 \] ### Step 5: Nucleophilic Attack by Iodide Ion The iodide ion (\( I^- \)) from HI will now act as a nucleophile and attack the carbocation, leading to the formation of the final product: \[ CH_3-CH_2-CH(CH_3)-CH_3 + I^- \rightarrow CH_3-CH_2-CH(I)-CH_3 \] ### Step 6: Final Product The final product formed from the reaction is: \[ CH_3-CH_2-CH(I)-CH_3 \] This compound is 1-iodobutane. ### Summary of Reaction The overall reaction can be summarized as: \[ CH_3-CH(CH_3)-CH(OH)-CH_2-CH_3 + HI \xrightarrow{\text{Heated}} CH_3-CH_2-CH(I)-CH_3 + H_2O \] ---

To solve the reaction of the compound \( CH_3-CH(CH_3)-CH(OH)-CH_2-CH_3 \) with HI when heated, we will follow these steps: ### Step 1: Identify the Reactants The reactant is \( CH_3-CH(CH_3)-CH(OH)-CH_2-CH_3 \) and it will react with hydroiodic acid (HI). ### Step 2: Protonation of the Alcohol When HI is added, the hydroxyl group (-OH) will be protonated by the \( H^+ \) from HI. This leads to the formation of water (H2O) and a carbocation. The reaction can be represented as: \[ CH_3-CH(CH_3)-CH(OH)-CH_2-CH_3 + H^+ \rightarrow CH_3-CH(CH_3)-C^+(H_2O)-CH_2-CH_3 \] ...
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NARAYNA-HALOALKANE AND HALOARENES-EXERCISE - 3
  1. The product C is CH(3).CH(2).C-=CH+HCl rarrBoverset(HI)rarrC

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  2. For the following (i) I^(-) (ii) Cl^(-) (iii) Br^(-) the increasin...

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  3. In the reaction CH3-overset(CH3)overset(|)(CH)-CH(OH)-CH2-CH3 +HIovers...

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  4. Which of the following undergoes nucleophilic substitution exclusively...

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  5. C2H5Clunderset(Ag2O)overset("Moist")rarr(A)overset(Al2O3)underset(360^...

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  6. In which alkyl halide SN^(2) mechanism is favoured maximum

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  7. When alkyl halide is heated with dry Ag(2)O. It produces :

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  8. H2C-underset(CH3)underset(|)(CH)-CH=CH2+HBrrarrA

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  9. In a S(N^(2)) substitution reaction of the type R-Br+Cl^(-)overset("...

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  10. Ethyl chloride reats with sodium ethoxide to form a compound 'A' which...

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  11. In a S(N^(2)) substitution reaction of the type R-Br+Cl^(-)overset("...

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  12. Which one of the following has the highest relative rate ?

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  13. Trichloroacetaldehyde, C Cl(3)CHO reacts with chlorobenzene in presenc...

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  14. Propionic acid with Br(2)/P yields a dibromo product. Its structure wo...

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  15. Which of the following reactions is an example of nucleophilic substit...

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  16. Consider the following reaction C2H5Cl+AgCNoverset("EtOH"//H2O)rarrX ...

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  17. The best method for the conversion of an alcohol into an alkyl chlori...

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  18. The correct order of increasing reactivity of C –X bond towards nucleo...

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  19. Which one is most reactive towards S(N)1 reactions ?

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  20. In the following reaction C2H6C(CH3)(C6H5)Br

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