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H2C-underset(CH3)underset(|)(CH)-CH=CH2+...

`H_2C-underset(CH_3)underset(|)(CH)-CH=CH_2+HBrrarrA`

A

`CH_3underset(CH_3)underset(|)(CH)-underset(Br)underset(|)(CH)-CH_3`

B

`CH_3underset(CH_3)underset(|)(CH)-CH_2-CH_3Br`

C

`CH_3-overset(Br)overset(|)underset(CH_3)underset(|)(C)-CH_2CH_3`

D

`CH_3-underset(Br)underset(|)(CH)-underset(CH_3)underset(|)(CH)-CH_3`

Text Solution

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The correct Answer is:
To solve the reaction of H₂C(CH₃)(CH)=CH₂ with HBr, we will follow the mechanism of electrophilic addition. Here’s a step-by-step breakdown of the reaction: ### Step 1: Identify the Reactants The reactant is H₂C(CH₃)(CH)=CH₂, which is an alkene. The alkene has a double bond between the carbon atoms, making it a site for electrophilic attack. **Hint:** Recognize that alkenes are reactive due to the presence of a double bond. ### Step 2: Electrophilic Attack When HBr is added to the alkene, the H⁺ from HBr acts as an electrophile and attacks the double bond. The double bond between the carbon atoms breaks, and one of the carbon atoms forms a bond with the hydrogen atom. **Hint:** Electrophiles are species that seek electrons and will attack regions of high electron density, like the double bond in alkenes. ### Step 3: Formation of Carbocation As the H⁺ attaches to one of the carbon atoms, a carbocation is formed on the adjacent carbon atom. The stability of the carbocation is crucial; in this case, a secondary carbocation is formed, which is more stable than a primary carbocation. **Hint:** The stability of carbocations increases with the number of alkyl groups attached to the positively charged carbon. ### Step 4: Nucleophilic Attack by Bromide Ion The Br⁻ ion, which is the nucleophile from the dissociation of HBr, will then attack the positively charged carbocation. This results in the formation of the final product. **Hint:** Nucleophiles are species that donate electrons and will attack positively charged centers, such as carbocations. ### Step 5: Final Product The final product of the reaction will be a bromoalkane, specifically 1-bromo-2-methylpropene. **Hint:** Always check the structure of the final product to ensure that it matches the expected outcome based on the mechanism. ### Summary of the Reaction The overall reaction can be summarized as: \[ H_2C(CH_3)(CH)=CH_2 + HBr \rightarrow 1-bromo-2-methylpropene \] ### Final Note Understanding the mechanism of electrophilic addition, including the formation of carbocations and the role of nucleophiles, is key to predicting the products of reactions involving alkenes and hydrogen halides. ---
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NARAYNA-HALOALKANE AND HALOARENES-EXERCISE - 3
  1. In which alkyl halide SN^(2) mechanism is favoured maximum

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  2. When alkyl halide is heated with dry Ag(2)O. It produces :

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  3. H2C-underset(CH3)underset(|)(CH)-CH=CH2+HBrrarrA

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  4. In a S(N^(2)) substitution reaction of the type R-Br+Cl^(-)overset("...

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  5. Ethyl chloride reats with sodium ethoxide to form a compound 'A' which...

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  6. In a S(N^(2)) substitution reaction of the type R-Br+Cl^(-)overset("...

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  7. Which one of the following has the highest relative rate ?

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  8. Trichloroacetaldehyde, C Cl(3)CHO reacts with chlorobenzene in presenc...

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  9. Propionic acid with Br(2)/P yields a dibromo product. Its structure wo...

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  10. Which of the following reactions is an example of nucleophilic substit...

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  11. Consider the following reaction C2H5Cl+AgCNoverset("EtOH"//H2O)rarrX ...

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  12. The best method for the conversion of an alcohol into an alkyl chlori...

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  13. The correct order of increasing reactivity of C –X bond towards nucleo...

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  14. Which one is most reactive towards S(N)1 reactions ?

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  15. In the following reaction C2H6C(CH3)(C6H5)Br

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  16. Which of the following is the least reactive towards nucleophile?

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  17. Methyl bromide reacts with AgF to give methyl fluoride and silver brom...

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  18. The correct order of reactivity of the halides ethyl chloride (I) iso-...

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  19. The order of rate of hydrolysis of alkyl halides 1^(@),2^(@),3^(@) and...

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  20. Which one is most reactive towards S(N)1 reactions ?

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