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Which one of the following statements re...

Which one of the following statements related to lanthanons is incorrect ?

A

Ce (+4) solutions are widely used as oxidizing agent in volumetric analysis

B

Europium shows +2 oxidation state

C

The basicity decreases as the ionic radius decreases from Pr to Lu

D

All the lanthanons are much more reactive than aluminimum

Text Solution

Verified by Experts

The correct Answer is:
D

(a) `Ce^(+4)` is a good oxidizing agent and easily converted into `Ce^(+3)`
(b) `Eu(63) = 4f^(7)5d^(0)6s^(2)`, `Eu^(+2) = 4f^(7)`
(c) In lanthanoids series .Ce. to .Lu. ionic radius regular decreases of hydroxide decrease.
(d) Lanthanons are less reactive than aluminium due to high IP (Lanthanoid contraction)
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