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The compexes [Co(NH(3))(6)][Cr(C(2)O(4))...

The compexes `[Co(NH_(3))_(6)][Cr(C_(2)O_(4))_(3)]` and `[Cr(NH_(3))_(6)][Co(C_(2)O_(4))_(3)]`

A

geometrical isomerism

B

isonisation energy

C

coordination isomerism

D

linkage isomerism

Text Solution

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Coordination isomerism is possible when both positive and negative ions of a salt are complex ions and the two isomers differ in distribution of ligands in the cation and the anion.
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Explore conceptually related problems

The complexes |Co(NH_(3))_(6)||Cr(C_(2)O_(4))_(3)| and |Cr(NH_(3))_(6)||Co(CrO_(4))_(3)| are

The IUPAC name of [Co(NH_(3))_(6)][Cr(C_(2)O_(4))_(3)] is :

The complexes [Co(NH_(3))_(6)][C(CN)_(6)] and [Cr(NH_(3))_(6)][Co(CN)_(6)] are the examples of which type of isomerism ?

How can be the following pair of isomers be distinguished from one another I [Co(NH_(3))_(6)][Cr(NO_(2))_(6)] and (II) [Cr(NH_(3))_(6)][Co(No_(2))_(6)] I [Cr(NH_(3))_(6)[Cr(No_(2))_(6)] and (II) [Cr(NH_(3))_(4)(No_(2))_(2)][Cr(NH_(3))_(2)(NO_(2))_(4)] .

Which isomerism is exhibited by [Co(NH_(3))_(6)][Cr(CN)_(6)] and [Cr(NH_(3))_(6)][Co(CN)_(6)] ?

Which would exhibit ionisation isomerism (a) p[Co(NH_(3))_(6)][(C_(2)O_(4))_(3)] (b) [Co(NH_(3))_(5)Br]^(2+)SO_(4)^(2-) (c ) K_(3)[Fe(CN)_(6)] K_(3)[Fe(C_(2)O_(4))_(3)] .

NARAYNA-CO-ORDINATE COMPOUNDS -Exercise-4
  1. The compexes [Co(NH(3))(6)][Cr(C(2)O(4))(3)] and [Cr(NH(3))(6)][Co(C(2...

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  2. One mole of complex compound Co(NH3)5Cl3 gives 3 moles of ions on diss...

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  3. The primary and secondary valencies of chromium in the complex ion, di...

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  4. In the complex with formula MCl(3).4H(2)O the co-ordination number of ...

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  5. The molar ionic conductances of octahedral complexes. (I) PtCl(4).5N...

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  6. The coordination number of a central metal atom in a complex is determ...

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  7. Among the following which are ambidentate ligands? (a) NO(2)^(-) (...

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  8. The number of donor sites in dimethyl glyoxime, glycinato, diethylene ...

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  9. The IUPAC name of the coordination compound K3[Fe(CN)6] is:

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  10. Which one of the following has largest number of isomers?

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  11. Which of the following compounds shows optical isomerism?

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  12. In which of the following pairs both the complexes do not show optical...

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  13. Of the following, the optical isomers are

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  14. Which kind of isomerism is shown by Co (NH(3))(4) Br(2) Cl ?

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  15. Which of the following does not have optical isomer

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  16. The complex K(3)[Fe(CN)(6)] should have a spin only magentic of

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  17. Which of the following complex is an outer orbital complex?

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  18. The correct order of magnetic moments (spin values in B.M.) among is:

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  19. Which one of the cyano complexes would exhibit the lowest value of par...

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  20. Which of the following statements is not correct?

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  21. The species having tetrahedral shape is

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