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Among the following metal carbonyls, the...

Among the following metal carbonyls, the `C-O` bond order is lowest in

A

`[V (CO)_(6)]^(-)`

B

`[Fe(CO)_(5)]`

C

`[Cr(CO)_(6)]`

D

`[Mn(CO)_(6)]^(+)`

Text Solution

Verified by Experts

The correct Answer is:
A

As increase of electron density back bonding tendence of `pi` bond increases, so C-O bond order decreases.
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